‘玉露香’梨不同采摘期及贮藏期果实品质变化分析

doi:10.16420/j.issn.0513-353x.2024-0741

摘要/Abstract

摘要： 为明晰不同采摘期和贮藏期‘玉露香’梨（Pyrus bretschneideri‘Yuluxiang’）果实品质变化规律，以露地栽培的‘玉露香’梨为对象，分别于花后140、145和150 d采摘果实，测定有机酸、可溶性糖、挥发性成分，以及不同贮藏期的品质指标。有机酸采用液相色谱仪检测，可溶性糖采用液相色谱—质谱联用仪检测，挥发性成分采用顶空—气相色谱—离子迁移谱联用仪和顶空—固相微萃取—气相色谱质谱联用仪检测。结果表明，随着采摘期延长，果实硬度逐渐下降，花后150 d显著低于140 d，可溶性固形物显著升高，总酸变化不显著；果皮和果肉中不同有机酸含量波动变化，其中果皮中奎宁酸含量最高，在花后150 d显著下降，果肉中苹果酸含量最高，先显著上升后下降；除花后150 d梨果皮中山梨糖醇含量显著下降，其他可溶性糖组分含量在果皮果肉中均随采摘期延长而上升，其中果皮中蔗糖、葡萄糖、果糖含量均在花后145 d显著升高，果肉中葡萄糖、果糖含量均显著升高，蔗糖、山梨糖醇含量变化差异不显著；在果实中共鉴定出97种挥发性成分，以醛类物质为主，共筛选出7种特征香气，花后140 d梨果实特征香气成分为1-辛烯-3-酮、反式-2-壬烯醛、（E,E）-2,4-壬二烯醛和2-正戊基呋喃，正丁醛、β-环柠檬醛为花后145和140 d梨果实特征香气。花后150 d梨果实特征香气为异丁酸乙酯。随着贮藏时间延长，不同采摘期的梨果实硬度均持续下降，失重率持续上升，与花后150 d相比，花后140、145 d采摘的梨果实在60 d贮藏期内品质更佳。推迟采摘果实风味更佳，适当早采利于贮藏期内品质保持，宜根据上市及贮藏需求选择采摘期。

关键词: 梨, 采摘期, 品质, 挥发性成分, 贮藏期

Abstract:

To clarify the variation of fruit quality of‘Yuluxiang’pear（Pyrus bretschneideri）at different picking stages and storage times，the organic acids，soluble sugars，volatile compounds and storage quality indexes of fruits were determined respectively on the 140 d，145 d and 150 d after flowering. Among them，organic acids and soluble sugars were detected by High Performance Liquid Chromatography and Liquid Chromatograph-Mass Spectrometer，respectively. Volatile compounds were detected by Headspace gas chromatography-ion mobility spectrometry and Headspace solid-phase microextraction-gas chromatography-mass spectrometry. The results showed that with the ripening of the fruit，the firmness of‘Yuluxiang’pear decreased gradually which the 150 d after flowering significantly lower than the 145 d. The soluble solids increased significantly and then decreased slightly at different picking stages. There was no significant difference in the change of total acid. The content of different organic acids in the peel and pulp had different trends at different picking stages. Among them，the content of quinic acid in the peel was the highest，decreasing significantly on the 150 d after flowering，while the content of malic acid in the pulp was the highest，increasing significantly at first and then decreasing significantly. Except for sorbitol content decreased significantly in the peel on the 150 d after flowering，the content of other soluble sugars increased with fruit ripening. Especially for the contents of sucrose，glucose，and fructose in peel，glucose and fructose in pulp were increased significantly. A total of 97 volatile compounds in‘Yuluxiang’pear were identified，in which aldehydes as the dominant substances. 7 volatile compounds were screened and confirmed as characteristic compounds. The characteristic volatile compounds of‘Yuluxiang’pear on the 140 d after flowering were 1-Octen-3-one，（E）-2-Nonenal，（E,E）-2,4-Nonadienal，Furan，2-pentyl-，Butanal，and β-Cyclocitral，among which the Butanal and β-Cyclocitral were the characteristic volatile compounds on the 145 d after flowering. The characteristic volatile compound of‘Yuluxiang’pear on the 150 d after flowering was Ethyl-2-methylproanoate. With the extension of storage time，the firmness of‘Yuluxiang’pear at different picking stages were decreased and the weight loss rate were increased. The quality of‘Yuluxiang’pear picked on the 140 d and 145 d after flowering was better than those on the 150 d when stored for 60 d. It can be concluded that the flavor of ‘Yuluxiang’pear was better picked later，and the quality for storage was better picked earlier. It is advisable to choose the harvest period according to the market and storage needs

Key words: pear, picking stage, quality, volatile compound, storage time

吴丹丹, 林梦桦, 李亚辉, 梁颖, 张志勇. ‘玉露香’梨不同采摘期及贮藏期果实品质变化分析[J]. 园艺学报, 2025, 52(6): 1553-1574.

WU Dandan, LIN Menghua, LI Yahui, LIANG Ying, and ZHANG Zhiyong. The Fruit Quality Variation of‘Yuluxiang’Pear at Different Picking Stages and Storage Time[J]. Acta Horticulturae Sinica, 2025, 52(6): 1553-1574.

图/表 12

参考文献 45

[1]	Bai Xuerong, Zhou Fangyan, Zhang Shaoling, Geng Xinli, Zheng Heyun, Pu Yunfeng, Li Jie, Ren Xiaopu, Xie Bin, Wang Libin. 2024. Effects of different preservatives on the quality of fresh-cut Korla Fragrant Pears. Food Research and Development, 45 (10):36-43. (in Chinese)
	白雪蓉, 周芳艳, 张绍铃, 耿新丽, 郑贺云, 蒲云峰, 李婕, 任晓镤, 谢兵, 王利斌. 2024. 不同保鲜剂处理对鲜切库尔勒香梨品质的影响. 食品研究与开发, 45 (10):36-43.
[2]	Chen C H, Seal A G, Macrae E A, Wang M Y. 2011. Identifying volatile compounds associated with sensory and fruit attributes in diploid Actinidia chinensis(kiwifruit)using multivariate analysis. Euphytica, 181 (2):179-195.
[3]	Chen J Q, Lü J H, He Z S, Zhang F, Zhang S L, Zhang P L. 2020. Investigations into the production of volatile compounds in Korla fragrant pears (Pyrus sinkiangensis Yu). Food Chemistry,302:125337.
[4]	Chen Xuesen, Wang Nan, Peng Futian, Mao Zhiquan, Yin Chengmiao, Jiang Yuanmao, Ge Shunfeng, Hu Dagang, Li Yuanyuan, Du Yuanpeng, Yao Yuxin, Zhang Zongying. 2024. Advances in quality and maturity breeding of important deciduous fruit trees in China. Acta Horticulturae Sinica, 51 (1):8-26. (in Chinese)
	陈学森, 王楠, 彭福田, 毛志泉, 尹承苗, 姜远茂, 葛顺峰, 胡大刚, 李媛媛, 杜远鹏, 姚玉新, 张宗营. 2024. 中国重要落叶果树果实品质和熟期育种研究进展. 园艺学报, 51 (1):8-26.
[5]	Cheng Huan, Chen Jianle, Zhou Xiaozhou, Chen Rongrong, Liu Donghong, Ye Xingqian. 2016. Advances in identification and biosynthetic pathway of key aroma in fruits. Journal of Chinese Institute of Food Science and Technology, 16 (1):211-218. (in Chinese)
	程焕, 陈健乐, 周晓舟, 陈荣荣, 刘东红, 叶兴乾. 2016. 水果香气物质分析及合成途径研究进展. 中国食品学报, 16 (1):211-218.
[6]	Cliff M A, Toivonen P M A. 2017. Sensory and quality characteristics of‘Ambrosia’apples in relation to harvest maturity for fruit stored up to eight months. Postharvest Biology and Technology,132:145-153.
[7]	Ding Baopeng, Li Xiaobai, Lin Yujing, Hu Chaohui, Yang Ru, Wei Bolin, Cao Yifan, Bai Yulin, Yan Ruyu, Li Liulin. 2024. Cloning and bioinformatics analysis of the auxin nicotinamide synthase genes GH 3 in‘Yuluxiangli’. Journal of Shanxi Agricultural University(Natural Science Edition), 44 (3):14-23. (in Chinese)
	丁保朋, 李小白, 林雨静, 胡朝慧, 杨茹, 韦博霖, 曹一凡, 白钰琳, 闫如玉, 李六林. 2024. ‘玉露香梨’生长素烟酰胺合成酶基因GH3克隆及其生物信息特征研究. 山西农业大学学报(自然科学版), 44 (3):14-23.
[8]	Garriz P I, Alvarez H L, Colavita G M. 2008. Harvest date effects on fruit quality of“ABBÉ FETEL”Pears. Acta Horticulturae,(800):1019-1026.
[9]	Gemert V. 2011. Compilations of odour threshold values in air and water. The Netherlands: Oliemans Punter & Partners BV.
[10]	Guang Xinmei, Xu Chongzhi, Wang Xuchun, Lan Haipeng, Liu Yang. 2018. The variation law and related relationship of quality index of Korla fragrant pear during the picking period. Jiangsu Agricultural Sciences, 46 (19):118-121. (in Chinese)
	广新梅, 徐崇志, 王绪春, 兰海鹏, 刘扬. 2018. 采摘期内库尔勒香梨品质指标变化规律及相关关系. 江苏农业科学, 46 (19):118-121.
[11]	Guo Huangping, Li Xiaomei, Zhang Jiangong. 2001. New high quality medium ripe red pear variety‘Yuluxiang’(tentative name). Shanxi Fruits,(1):3-4. (in Chinese)
	郭黄萍, 李晓梅, 张建功. 2001. 优质中熟红梨新品种“玉露香”(暂定名). 山西果树,(1):3-4.
[12]	He Wanlin, Shi Lu, Lin Menghua, Li Yahui, Liang Ying, Zhang Zhiyong. 2024. Quality analysis of‘Akizuki’pear fruit(Pyrus pyrifolia)from different geographical origins by Gas Chromatography-lon Mobility Spectrometry. Food Science, 45 (5):118-125. (in Chinese)
	何婉琳, 施露, 林梦桦, 李亚辉, 梁颖, 张志勇. 2024. 基于气相色谱—离子迁移谱分析不同产地秋月梨品质差异. 食品科学, 45 (5):118-125.
[13]	Hu Zhehui, Liu Yuan, Wang Jiangbo, Zhang Hongyan, Wu Cuiyun, Xu Juan. 2022. Aroma and sensory qualities and their associated volatile components of three pear cultivars. Journal of Huazhong Agricultural University, 41 (4):217-225. (in Chinese)
	胡哲辉, 刘园, 王江波, 张红艳, 吴翠云, 徐娟. 2022. 3个品种梨香气感官品质与挥发性物质关联分析. 华中农业大学学报, 41 (4):217-225.
[14]	Huo Yueqing, Hu Hongju, Peng Shu’ang, Chen Qiliang. 2009. Contents and changes of organic acid in sand pears from different germplasm resources. Scientia Agricultura Sinica, 42 (1):216-223. (in Chinese)
	霍月青, 胡红菊, 彭抒昂, 陈启亮. 2009. 砂梨品种资源有机酸含量及发育期变化. 中国农业科学, 42 (1):216-223.
[15]	Jia Xiaohui, Wang Wenhui, Jiang Yunbin, Wang Zhihua, Du Yanmin, Tong Wei. 2016. Effects of harvest maturity on fruit quality and storage life of‘Yuluxiang’pears. Journal of Fruit Science, 33 (5):594-603. (in Chinese)
	贾晓辉, 王文辉, 姜云斌, 王志华, 杜艳民, 佟伟. 2016. 采收成熟度对‘玉露香’梨果实品质和耐贮性的影响. 果树学报, 33 (5):594-603.
[16]	Jia Z Y, Wang Y, Wang L, Zheng Y H, Jin P. 2022. Amino acid metabolomic analysis involved in flavor quality and cold tolerance in peach fruit treated with exogenous glycine betaine. Food Research International,157:111204.
[17]	Kaur S, Singh Gill M, Gill P P S, Jawandha S K, Singh N P. 2023. Influence of harvest date on storage quality of Asian Pear(Pyrus pyrifolia)fruit. Erwerbs-Obstbau, 65 (5):1331-1339.
[18]	Li J M, Zhang M Y, Li X L, Khan A, Kuamr S, Allan A C, Wang K L, Espley R V, Wang C H, Wang R Z, Cheng X, Yao G F, Qin M F, Qin M F, Sun M Y, Tegtmeier R, Liu H N, Wei W L, Ming M L, Zhao S L, Zhao K J, Song S S, Ni J N, An J P, Korban S S, Wu J. 2022a. Pear genetics:Recent advances,new prospects,and a roadmap for the future. Horticulture Research,9:uhab040.
[19]	Li Ting, Zhu Zihao, Wang Yiju, Feng Shouqian. 2023. Harvesting date influence on fruit quality of‘Packham’s Triumph’Pear. Journal of Shandong Agricultural University(Natural Science Edition), 54 (6):808-813. (in Chinese)
	李婷, 祝自豪, 王义菊, 冯守千. 2023. 采收期对‘盘克汉姆’梨果实品质的影响. 山东农业大学学报(自然科学版), 54 (6):808-813.
[20]	Li Wenyuan, Lin Menghua, Li Yahui, Yu Quanqi, Liang Ying, Zhang Zhiyong. 2024. Advances in metabolomics of pear fruit. Acta Horticulturae Sinica, 51 (7):1595-1609. (in Chinese)
	李文远, 林梦桦, 李亚辉, 于全琦, 梁颖, 张志勇. 2024. 梨果实代谢组学研究进展. 园艺学报, 51 (7):1595-1609.
[21]	Li X J, Qi L Y, Zang N N, Zhao L H, Sun Y Q, Huang X T, Wang H Y, Yin Z P, Yin Z P, Wang A. 2022b. Integrated metabolome and transcriptome analysis of the regulatory network of volatile ester formation during fruit ripening in pear. Plant Physiology and Biochemistry,185:80-90.
[22]	Lin M H, Li Y H, Gao Q C, Shi L, He W L, Li W Y, Liang Y, Zhang Z Y. 2024. Dynamic changes in physicochemical and transcriptional expression profiles of mulberry(Morus alba L.)fruit during ripening. Food Bioscience,57:103606.
[23]	Liu Bailin, Jia Xiaohui, Du Yanmin, Cui Jianchao, Wang Wenhui. 2023. Effects of harvest period on the fruit quality and storage life of‘Xinli 7’ pear during cold storage. China Fruits,(5):103-109,114. (in Chinese)
	刘佰霖, 贾晓辉, 杜艳民, 崔建潮, 王文辉. 2023. 采收期对新梨7号果实冷藏期间品质及耐贮性的影响. 中国果树,(5):103-109,114.
[24]	Liu W J, Zhang Y Y, Ma R R, Yu M L. 2022. Comparison of aroma trait of the white-fleshed peach‘Hu Jing Mi Lu’ and the yellow-fleshed peach‘Jin Yuan’ based on odor activity value and odor characteristics. Horticulturae, 8 (3):245-261.
[25]	Pan Yan, Meng Xintao, Che Fengbin, Xue Sulin, Zhang Ting, Zhao Shirong, Liao Kang. 2016. Metabolic profiles of sugar metabolism and respiratory metabolism of Korla Pear(Pyrus sinkiangensis Yu)throughout fruit development and ripening. Scientia Agricultura Sinica, 49 (17):3391-3412. (in Chinese)
	潘俨, 孟新涛, 车风斌, 薛素琳, 张婷, 赵世荣, 廖康. 2016. 库尔勒香梨果实发育成熟的糖代谢和呼吸代谢响应特征. 中国农业科学, 49 (17):3391-3412.
[26]	Qin Qiaoping, Zhang Shanglong, Xie Ming, Chen Junwei. 2005. Progress on the research of the molecular regulation of sugar content and composition in fruit. Journal of Fruit Science, 22 (5):519-525. (in Chinese)
	秦巧平, 张上隆, 谢鸣, 陈俊伟. 2005. 果实糖含量及成分调控的分子生物学研究进展. 果树学报, 22 (5):519-525.
[27]	Shi Lu, Gao Qingchao, Li Yahui, Liang Ying, Zhang Zhiyong. 2022. Research progress and prospects of potential technology application in pear fruit quality. Jiangsu Journal of Agricultural Sciences, 38 (2):567-576. (in Chinese)
	施露, 高庆超, 李亚辉, 梁颖, 张志勇. 2022. 梨果实品质的研究进展与潜在技术应用展望. 江苏农业学报, 38 (2):567-576.
[28]	Tkacz K, Chmielewska J, Turkiewicz I P, Nowicka P. 2020. Dynamics of changes in organic acids,sugars and phenolic compounds and antioxidant activity of sea buckthorn and sea buckthorn-apple juices during malolactic fermentation. Food Chemistry,332:127382.
[29]	Wang L, Chen Y, Wang S K, Xue H B, Su Y L, Yang J, Li X G. 2017. Identification of candidate genes involved in the sugar metabolism and accumulation during pear fruit post-harvest ripening of‘Red Clapp’s Favorite’(Pyrus communis L.) by transcriptome analysis. Hereditas, 155 (1):11.
[30]	Wang Zhihua, Wang Wenhui, Tong Wei, Hang Bo, Du Yanming, Jia Xiaohui. 2015. Effect of harvest time on postharvest physiology and quality of red fragrant pear. South China Fruits, 44 (6):91-95. (in Chinese)
	王志华, 王文辉, 佟伟, 杭博, 杜艳民, 贾晓辉. 2015. 采收期对“红香酥”梨果实采后生理和品质的影响. 中国南方果树, 44 (6):91-95.
[31]	Wu J Y, Fan J B, Li Q H, Jia L T, Xu L L, Wu X, Wang Z W, Li H X, Qi K J, Qiao X, Zhang S L, Yin H. 2022. Variation of organic acids in mature fruits of 193 pear(Pyrus spp.)cultivars. Journal of Food Composition and Analysis,109:104483.
[32]	Xu H R, Pan S, Wang J B, Ye T C, Yan M, Liang X M, Qian G L, Yan T C, Xin G. 2024. Comparative characterization of volatile organic compounds and aroma profiles in 10 Actinidia arguta cultivars by gas chromatography-mass spectrometry(GC-MS),sensory analysis,and odor activity value(OAV)combined with chemometrics. Journal of Food Composition and Analysis,133:106450.
[33]	Xu L, Zang E H, Sun S Y, Li M H. 2023. Main flavor compounds and molecular regulation mechanisms in fruits and vegetables. Critical Reviews in Food Science and Nutrition, 63 (33):11859-11879.
[34]	Yang X B, Chen Q H, Liu S C, Hong P Z, Zhou C X, Zhong S Y. 2024. Characterization of the effect of different cooking methods on volatile compounds in fish cakes using a combination of GC-MS and GC-IMS. Food Chemistry-X,22:101291.
[35]	Yao Gaifang, Zhang Shaoling, Cao Yufen, Liu Jun, Wu Jun, Yuan Jiang, Zhang Huping, Xiao Changcheng. 2010. Characteristics of components and contents of soluble sugars in pear fruits from different species. Scientia Agricultura Sinica, 43 (20):4229-4237. (in Chinese)
	姚改芳, 张绍铃, 曹玉芬, 刘军, 吴俊, 袁江, 张虎平, 肖长城. 2010. 不同栽培种梨果实中可溶性糖组分及含量特征. 中国农业科学, 43 (20):4229-4237.
[36]	Yin H, Wu J Y, Fan J B, Zhang W W, Li Q H, Jia L T, Wu X, Wang Z W, Li H X, Qi K J, Qiao X, Zhang S L. 2024. Profiling of soluble sugar compositions in mature fruits of a diverse pear(Pyrus spp.)germplasm by UPLC. Journal of Food Composition and Analysis,132:106281.
[37]	Yu C Y, Cheng H Y, Cheng R, Qi K J, Gu C, Zhang S L. 2019. Expression analysis of sorbitol transporters in pear tissues reveals that PbSOT6/20 is associated with sorbitol accumulation in pear fruits. Scientia Horticulturae,243:595-601.
[38]	Zhang Jia, Nie Jiyun, Zhang Hui, Li Jing, Li Ye. 2019. Evaluation indexes for blueberry quality. Scientia Agricultura Sinica, 52 (12):2128-2139. (in Chinese)
	张佳, 聂继云, 张惠, 李静, 李也. 2019. 越橘品质指标评价. 中国农业科学, 52 (12):2128-2139.
[39]	Zhang Jingzeng, Wang Xiaoning, Feng Meijing, Ma Hui, Zhang Haixia, Zhang Binglong, Zhang Yuxing, Xu Jianfeng. Effects of harvest time on the quality and storability of‘Yali’pear. China Fruits,(9):21-24. (in Chinese)
	张静增, 王晓宁, 丰美静, 马辉, 张海霞, 张炳龙, 张玉星, 许建锋. 2021. 采收期对‘鸭梨’果实品质及耐贮性的影响. 中国果树,(9):21-24.
[40]	Zhang Yaxin, Li Xuan, Hu Jiaxing, Bi Jinfeng, Liu Xia. 2024. Research progress in taste characteristics of fruits and fruit products and methods for their regulation. Food Science, 45 (14):299-311. (in Chinese)
	张雅欣, 李旋, 胡佳星, 毕金峰, 刘霞. 2024. 水果及其制品滋味特征及调控方法研究进展. 食品科学, 45 (14):299-311.
[41]	Zhang Yue, Zhu Yin, Ye Huoxiang, Tan Junfeng, Liu Linmin, Lü Haipeng, Yu Liaoyuan, Lin Zhi. 2017. Comparative study on the contents of the major chemical constituents of fragrant tea from different producing areas. Food Science, 38 (22):184-191. (in Chinese)
	张悦, 朱荫, 叶火香, 谭俊峰, 刘林敏, 吕海鹏, 俞燎远, 林智. 2017. 不同产地香茶的主要化学成分含量的差异分析. 食品科学, 38 (22):184-191.
[42]	Zhao Xin, Liang Kehong, Zhu Hong, Liu Li, Wang Jing. 2020. Comparative research on nutritional quality and flavor compounds of different pear varieties. Journal of Food Safety and Quality, 11 (21):7797-7805. (in Chinese)
	赵欣, 梁克红, 朱宏, 刘莉, 王靖. 2020. 不同品种梨营养品质及风味物质比较研究. 食品安全质量检测学报, 11 (21):7797-7805.
[43]	Zhao Yingli, Zhang Wei, Yang Zhiguo, Wang Liang, Chen Huiyan, Li Chao. 2023. Effect of soluble solids content on cold storage quality and core browning of‘Yuluxiang’pear. China Fruits,(11):27-31. (in Chinese)
	赵迎丽, 张微, 杨志国, 王亮, 陈会燕, 李超. 2023. 可溶性固形物含量对玉露香梨冷藏品质及果心褐变的影响. 中国果树,(11):27-31.
[44]	Zhou Nan, Huang Jun, Wen Ping, He Pei, Liu Jitang, Zhou Rongqing. 2022. Effects of seasons and daqu-making process on the microbial community structure and metabolites of bran cuqu. Science and Technology of Food Industry, 43(1):155-162. (in Chinese)
	周楠, 黄钧, 文平, 何培, 刘记堂, 周荣清. 2022. 季节及制曲工艺对麸醋曲微生物群落结构及代谢组分的影响. 食品工业科技, 43 (1):155-162.
[45]	Zlatić E, Zandnik V, Fellman J, Demšar L, Hribar J, Čejić Ž, Vidrih R. 2016. Comparative analysis of aroma compounds in‘Bartlett’pear in relation to harvest date,storage conditions,and shelf-life. Postharvest Biology and Technology,117:71-80.

花后天数/d Days after flowering	单果质量/g Fruit weight	硬度/（kg · cm^-2） Firmness	可溶性固形物/% Soluble solids	总酸/（g · kg^-1） Total acid
140	301.59 ± 3.15 a	3.23 ± 0.24 a	11.27 ± 0.62 b	0.87 ± 0.05 a
145	304.73 ± 6.26 a	2.93 ± 0.29 ab	12.80 ± 0.15 a	0.88 ± 0.09 a
150	307.20 ± 10.87 a	2.68 ± 0.08 b	11.77 ± 0.42 ab	0.74 ± 0.14 a

花后天数/d Days after flowering	单果质量/g Fruit weight	硬度/（kg · cm^-2） Firmness	可溶性固形物/% Soluble solids	总酸/（g · kg^-1） Total acid
140	301.59 ± 3.15 a	3.23 ± 0.24 a	11.27 ± 0.62 b	0.87 ± 0.05 a
145	304.73 ± 6.26 a	2.93 ± 0.29 ab	12.80 ± 0.15 a	0.88 ± 0.09 a
150	307.20 ± 10.87 a	2.68 ± 0.08 b	11.77 ± 0.42 ab	0.74 ± 0.14 a

类别 Type	化合物 Volatile compound			CAS号 Chemical Abstract Service		分子式 Molecular formula	相对分子质量 MW		保留指数 RI	保留时间/s RT		相对迁移时间 DT
醇类Alcohols	3-庚醇3-Heptanol			589-82-2		C₇H₁₆O	116.2		899.3	252.383		1.33783
	顺-2-戊烯醇（Z）-2-Penten1ol			1576-95-0		C₅H₁₀O	86.1		762.1	188.713		1.44506
	1-戊烯-3-醇Pent-1-en-3-ol			616-25-1		C₅H₁₀O	86.1		670.6	158.603		1.34867
	乙二醇二甲醚1，2-Dimethoxyethane			110-71-4		C₄H₁₀O₂	90.1		651.7	154.307		1.30380
	乙二醇丁醚2-Butoxyethanol			111-76-2		C₆H₁₄O₂	118.2		906.1	256.891		1.18231
	2-己醇2-Hexanol			626-93-7		C₆H₁₄O	102.2		816.3	210.419		1.26772
	4-己烯-1-醇4-Hexen-1-ol			6126-50-7		C₆H₁₂O	100.2		886.2	244.761		1.46307
	正己醇1-Hexanol			111-27-3		C₆H₁₄O	102.2		878.1	240.506		1.32130
	反式-2-己烯-1-醇（E）-2-Hexen-1-ol			928-95-0		C₆H₁₂O	100.2		873.4	238.081		1.18006
醛类Aldehydes	2-甲基丁醛2-Methylbutyraldehyde			96-17-3		C₅H₁₀O	86.1		661.5	156.524		1.16917
	2-己烯醛2-Hexenal			505-57-7		C₆H₁₀O	98.1		858.6	230.792		1.51165
	反式-2-庚醛Trans-2-Heptenal			18829-55-5		C₇H₁₂O	112.2		960.5	295.962		1.25501
	庚醛Heptanal			111-71-7		C₇H₁₄O	114.2		899.0	252.372		1.34091
	3-甲基-2-丁烯醛3-Methyl-2-butenal			107-86-8		C₅H₈O	84.1		775.5	193.022		1.11013
	正戊醛n-Pentanal			110-62-3		C₅H₁₀O	86.1		700.5	166.832		1.19381
	异戊醛3-Methyl butanal			590-86-3		C₅H₁₀O	86.1		656.4	155.592		1.18117
	（E,E）-2,4-己二烯醛（E,E）-2,4-Hexadienal			142-83-6		C₆H₈O	96.1		911.1	260.399		1.12014
	反式-2-己烯醛（E）-2-Hexenal			6728-26-3		C₆H₁₀O	98.1		832.5	217.925		1.18148
	反式-2-戊烯醛Trans-2-Pentenal			1576-87-0		C₅H₈O	84.1		749.9	183.655		1.10252
	正丁醛Butanal			123-72-8		C₄H₈O	72.1		592.0	141.750		1.28560
	2-甲基丙烯醛2-Methyl-2-propenal			78-85-3		C₄H₆O	70.1		579.6	139.235		1.05629
酸类Acids	2-甲基戊酸2-Methyl-pentanoic acid			97-61-0		C₆H₁₂O₂	116.2		956.9	293.057		1.25589
	丙酸Propanoic acid		79-09-4			C₃H₆O₂	74.1		735.9	179.018		1.10545
	异戊酸3-Methylbutanoic acid		503-74-2			C₅H₁₀O₂	102.1		850.2	226.431		1.51331
	丁酸Butanoic acid		107-92-6			C₄H₈O₂	88.1		790.4	198.949		1.40465
酮类Ketones	2-己酮2-Hexanone		591-78-6			C₆H₁₂O	100.2		775.3	193.758		1.18844
	3-辛酮3-Octanone		106-68-3			C₈H₁₆O	128.2		992.9	321.872		1.30203
	1-辛烯-3-酮1-octen-3-one		4312-99-6			C₈H₁₄O	126.2		981.1	312.219		1.27109
	环己酮Cyclohexanone		108-94-1			C₆H₁₀O	98.1		889.8	246.682		1.14241
	2-戊酮2-Pentanone		107-87-9			C₅H₁₀O	86.1		674.0	159.624		1.11070
	3-戊酮3-Pentanone		96-22-0			C₅H₁₀O	86.1		690.9	163.766		1.34928
	1-戊烯-3-酮1-Penten-3-one		1629-58-9			C₅H₈O	84.1		682.0	161.480		1.08078
	过氧化乙酰丙酮Acetoxyacetone		592-20-1			C₅H₈O₃	116.1		486.7	121.695		1.17657
烯烃类Alkenes	β-蒎烯（-）-β-Pinene		18172-67-3			C₁₀H₁₆	136.2		962.5	297.486		1.21913
酯类Esters	甲酸异戊酯Isopentyl formate		110-45-2			C₆H₁₂O₂	116.2		782.8	196.710		1.26577
	异丁酸乙酯Ethyl 2-methylpropanoate		97-62-1			C₆H₁₂O₂	116.2		755.3	186.152		1.19126
	丙烯酸乙酯Ethyl acrylate		140-88-5			C₅H₈O₂	100.1		698.1	165.948		1.42123
	甲酸丁酯Butyl formate		592-84-7			C₅H₁₀O₂	102.1		710.5	170.106		1.19209
	乙酸叶醇酯（Z）-3-hexenyl acetate		3681-71-8			C₈H₁₄O₂	142.2		1 013.1	342.702		1.32678
	巴豆酸乙酯Ethyl trans-2-butenoate		623-70-1			C₆H₁₀O₂	114.1		865.7	234.156		1.57582
	乙酸丁酯1-Butyl acetate		123-86-4			C₆H₁₂O₂	116.2		806.6	206.068		1.23544
	丁酸乙酯Ethyl butanoate		105-54-4			C₆H₁₂O₂	116.2		794.3	200.669		1.55681
	乙酸乙酯Acetic acid ethyl ester		141-78-6			C₄H₈O₂	88.1		602.6	143.930		1.09457
	乙酸甲酯Methyl acetate		79-20-9			C₃H₆O₂	74.1		555.5	134.447		1.19033
	乙酸己酯Hexyl acetate		142-92-7			C₈H₁₆O₂	144.2		1 008.4	337.531		1.40827
其他类Others	3-乙基-2-甲基吡嗪 2-Ethyl-3-methylpyrazine		15707-23-0			C₇H₁₀N₂	122.2		992.1	321.076		1.17599
	2,6-二甲基吡啶 2,6-Dimethylpyridine		108-48-5			C₇H₉N	107.2		887.2	245.193		1.46106
	2,5-二甲基呋喃2,5-Dimethylfuran		625-86-5			C₆H₈O	96.1		696.5	165.394		1.36108
	2-乙基呋喃2-Ethylfuran		3208-16-0			C₆H₈O	96.1		719.5	173.128		1.04219
	二丙基二硫Dipropyl disulfide		629-19-6			C₆H₁₄S₂	150.3		1 109.3	466.665		1.47526
类别 Type		化合物 Volatile compound			不同采摘期果皮挥发性成分峰面积 The peak area of the peel in different picking stages
类别 Type		化合物 Volatile compound			140 DAF			145 DAF			150 DAF
醇类Alcohols		3-庚醇3-Heptanol			289.67 ± 16.87			276.67 ± 13.94			265.76 ± 28.20
		顺-2-戊烯醇（Z）-2-Penten1ol			363.47 ± 23.72			278.65 ± 61.72			210.19 ± 34.51
		1-戊烯-3-醇Pent-1-en-3-ol			156.45 ± 1.86			148.64 ± 10.27			152.94 ± 2.90
		乙二醇二甲醚1，2-Dimethoxyethane			164.57 ± 21.30			183.53 ± 14.50			126.94 ± 17.74
		乙二醇丁醚2-Butoxyethanol			355.27 ± 10.17			368.37 ± 8.61			380.42 ± 21.07
		2-己醇2-Hexanol			ND			ND			ND
		4-己烯-1-醇4-Hexen-1-ol			131.04 ± 2.95			140.04 ± 17.23			129.54 ± 12.42
		正己醇1-Hexanol			46.05 ± 7.29			16.59 ± 1.85			14.24 ± 0.52
		反式-2-己烯-1-醇（E）-2-Hexen-1-ol			3 134.4 ± 10.62			3 111.35 ± 62.76			3 139.13 ± 49.57
醛类Aldehydes		2-甲基丁醛2-Methylbutyraldehyde			655.86 ± 33.58			552.26 ± 49.44			707.19 ± 13.05
		2-己烯醛2-Hexenal			18 125.60 ± 261.32			18 023.16 ± 333.01			17 921.4 ± 291.69
		反式-2-庚醛Trans-2-Heptenal			ND			ND			ND
		庚醛Heptanal			ND			ND			ND
		3-甲基-2-丁烯醛3-Methyl-2-butenal			ND			ND			ND
		正戊醛n-Pentanal			ND			ND			ND
		异戊醛3-Methyl butanal			ND			ND			ND
		（E,E）-2,4-己二烯醛（E,E）-2, 4-Hexadienal			236.13 ± 27.84			294.79 ± 71.87			272.48 ± 62.90
		反式-2-己烯醛（E）-2-Hexenal			522.73 ± 8.00			528.63 ± 23.47			542.06 ± 8.89
		反式-2-戊烯醛Trans-2-Pentenal			652.00 ± 11.27			656.85 ± 26.46			664.45 ± 13.58
		正丁醛Butanal			216.46 ± 4.02			163.57 ± 77.47			123.34 ± 21.30
		2-甲基丙烯醛2-Methyl-2-propenal			769.30 ± 66.34			700.40 ± 114.92			665.76 ± 30.30
酸类Acids		2-甲基戊酸2-Methyl-pentanoic acid			299.23 ± 8.83			288.85 ± 17.75			308.37 ± 30.19
		丙酸Propanoic acid			591.25 ± 13.66			603.87 ± 31.17			654.38 ± 3.58
		异戊酸3-Methylbutanoic acid			ND			ND			ND
		丁酸Butanoic acid			180.48 ± 4.54			165.61 ± 20.13			178.02 ± 5.67
酮类Ketones		2-己酮2-Hexanone			114.54 ± 4.74			113.60 ± 5.14			115.49 ± 2.27
		3-辛酮3-Octanone			ND			ND			ND
		1-辛烯-3-酮1-octen-3-one			ND			ND			ND
		环己酮Cyclohexanone			ND			ND			ND
		2-戊酮2-Pentanone			ND			ND			ND
		3-戊酮3-Pentanone			ND			ND			ND
		1-戊烯-3-酮1-Penten-3-one			188.86 ± 9.75			217.16 ± 2.15			301.87 ± 40.18
		过氧化乙酰丙酮Acetoxyacetone			691.52 ± 183.40			621.57 ± 54.21			549.11 ± 58.27
烯烃类Alkenes		β-蒎烯（-）-β-Pinene			94.88 ± 11.33			95.42 ± 18.69			91.44 ± 18.73
酯类Esters		甲酸异戊酯Isopentyl formate			146.47 ± 11.50			141.61 ± 9.70			148.83 ± 13.88
		异丁酸乙酯Ethyl 2-methylpropanoate			57.30 ± 2.81			58.42 ± 4.78			75.17 ± 5.33
		丙烯酸乙酯Ethyl acrylate			169.31 ± 9.19			195.61 ± 60.58			147.39 ± 9.43
		甲酸丁酯Butyl formate			1 545.28 ± 28.38			1 488.52 ± 191.94			1 786.14 ± 27.41
		乙酸叶醇酯（Z）-3-hexenyl acetate			ND			ND			ND
		巴豆酸乙酯Ethyl trans-2-butenoate			ND			ND			ND
		乙酸丁酯1-Butyl acetate			101.25 ± 4.74			63.72 ± 15.09			48.33 ± 3.58
		丁酸乙酯Ethyl butanoate			11 136.61 ± 349.64			11 024.93 ± 7.27			11 559.72 ± 231.53
		乙酸乙酯Acetic acid ethyl ester			1 279.46 ± 77.85			1 183.75 ± 379.92			1 107.19 ± 121.36
		乙酸甲酯Methyl acetate			248.17 ± 45.90			334.15 ± 65.70			176.14 ± 31.28
		乙酸己酯Hexyl acetate			180.77 ± 2.37			167.34 ± 18.10			174.45 ± 26.67
其他类Others		3-乙基-2-甲基吡嗪 2-Ethyl-3-methylpyrazine			291.71 ± 18.91			338.83 ± 17.25			292.43 ± 13.36
		2,6-二甲基吡啶2,6-Dimethylpyridine			104.68 ± 4.39			104.53 ± 10.99			106.77 ± 4.88
		2,5-二甲基呋喃2,5-Dimethylfuran			245.24 ± 2.51			230.30 ± 5.57			212.60 ± 10.63
		2-乙基呋喃2-Ethylfuran			ND			ND			ND
		二丙基二硫Dipropyl disulfide			777.05 ± 24.31			701.73 ± 25.55			394.89 ± 30.94
醇类Alcohols		3-庚醇3-Heptanol			ND			ND			ND
		顺-2-戊烯醇（Z）-2-Penten1ol			ND			ND			ND
		1-戊烯-3-醇Pent-1-en-3-ol			ND			ND			ND
		乙二醇二甲醚1，2-Dimethoxyethane			ND			ND			ND
		乙二醇丁醚2-Butoxyethanol			ND			ND			ND
		2-己醇2-Hexanol			2 511.61 ± 35.35			2 473.53 ± 67.51			2 306.54 ± 20.15
		4-己烯-1-醇4-Hexen-1-ol			83.37 ± 7.10			73.30 ± 5.49			80.03 ± 9.70
		正己醇1-Hexanol			214.77 ± 26.19			137.30 ±4 0.40			289.48 ± 92.09
		反式-2-己烯-1-醇（E）-2-Hexen-1-ol			2 691.55±128.98			2 582.66 ± 164.21			2 287.91 ± 226.15
醛类Aldehydes		2-甲基丁醛2-Methylbutyraldehyde			ND			ND			ND
		2-己烯醛2-Hexenal			ND			ND			ND
		反式-2-庚醛Trans-2-Heptenal			567.49 ± 36.42			535.37 ± 62.35			427.71 ± 67.28
		庚醛Heptanal			443.87 ± 36.92			382.24 ± 39.11			326.16 ± 40.41
		3-甲基-2-丁烯醛3-Methyl-2-butenal			119.27 ± 8.58			106.04 ± 3.00			114.69 ± 3.21
		正戊醛n-Pentanal			4 069.83 ± 81.83			4 009.21 ± 97.32			4 024.03 ± 70.64
		异戊醛3-Methyl butanal			289.50 ± 9.99			305.75 ± 19.82			277.66 ± 16.75
		（E,E）-2,4-己二烯醛（E,E）-2, 4-Hexadienal			41.38 ± 9.21			29.37 ± 6.95			29.34 ± 6.25
		反式-2-己烯醛（E）-2-Hexenal			861.86 ± 41.22			915.02 ± 27.66			974.39 ± 35.27
		反式-2-戊烯醛Trans-2-Pentenal			84.87 ± 8.51			72.72 ± 5.85			61.41 ± 6.13
		正丁醛Butanal			216.97 ± 22.39			222.41 ± 24.33			91.44 ± 23.56
		2-甲基丙烯醛2-Methyl-2-propenal			644.94 ± 18.75			541.88 ± 19.31			582.53 ± 16.63
酸类Acids		2-甲基戊酸2-Methyl-pentanoic acid			ND			ND			ND
		丙酸Propanoic acid			ND			ND			ND
		异戊酸3-Methylbutanoic acid			10 121.16 ± 86.88			8 822.95 ± 494.39			8 410.2 2± 392.84
		丁酸Butanoic acid			281.51 ± 8.79			269.43 ± 4.79			293.55 ± 2.41
酮类Ketones		2-己酮2-Hexanone			ND			ND			ND
		3-辛酮3-Octanone			71.55 ± 13.08			88.70 ± 16.07			102.35 ± 26.66
		1-辛烯-3-酮1-octen-3-one			234.81 ± 19.37			204.79 ± 30.31			129.73 ± 15.66
		环己酮Cyclohexanone			196.55 ± 13.13			175.53 ± 11.06			187.70 ± 6.14
		2-戊酮2-Pentanone			26.06 ± 3.14			26.98 ± 0.41			29.75 ± 1.38
		3-戊酮3-Pentanone			1 145.40 ± 59.47			1 058.28 ± 37.08			1 006.45 ± 51.49
		1-戊烯-3-酮1-Penten-3-one			261.60 ± 24.70			218.43 ± 14.40			193.89 ± 18.55
		过氧化乙酰丙酮Acetoxyacetone			570.85 ± 56.99			776.44 ± 70.76			458.48 ± 69.04
烯烃类Alkenes		β-蒎烯（-）-β-Pinene			74.42 ± 11.89			59.63 ± 11.52			58.90 ± 15.99
酯类Esters		甲酸异戊酯Isopentyl formate			ND			ND			ND
		异丁酸乙酯Ethyl 2-methylpropanoate			ND			ND			ND
		丙烯酸乙酯Ethyl acrylate			ND			ND			ND
		甲酸丁酯Butyl formate			ND			ND			ND
		乙酸叶醇酯（Z）-3-hexenyl acetate			62.65 ± 11.19			40.13 ± 7.46			26.89 ± 4.30
		巴豆酸乙酯Ethyl trans-2-butenoate			266.37 ± 70.37			336.66 ± 76.75			512.39 ± 51.63
		乙酸丁酯1-Butyl acetate			138.45 ± 9.40			121.19 ± 45.07			89.45 ± 13.99
		丁酸乙酯Ethyl butanoate			10 002.77 ± 84.56			9 549.11 ± 213.41			8 787.71 ± 251.88
		乙酸乙酯Acetic acid ethyl ester			1 240.37 ± 100.59			1 312.19 ± 137.25			845.61 ± 132.94
		乙酸甲酯Methyl acetate			349.65±149.14			456.5 ± 110.82			233.5 ± 52.94
		乙酸己酯Hexyl acetate			473.21 ± 80.62			326.13 ± 45.95			251.76 ± 37.56
其他类Others		3-乙基-2-甲基吡嗪 2-Ethyl-3-methylpyrazine			ND			ND			ND
		2,6-二甲基吡啶2,6-Dimethylpyridine			ND			ND			ND
		2,5-二甲基呋喃2,5-Dimethylfuran			ND			ND			ND
		2-乙基呋喃2-Ethylfuran			473.55 ± 22.12			403.84 ± 2.40			451.73 ± 39.80
		二丙基二硫Dipropyl disulfide			555.57 ± 75.44			330.14 ± 19.94			265.53 ± 7.71

类别 Type	化合物 Volatile compound			CAS号 Chemical Abstract Service		分子式 Molecular formula	相对分子质量 MW		保留指数 RI	保留时间/s RT		相对迁移时间 DT
醇类Alcohols	3-庚醇3-Heptanol			589-82-2		C₇H₁₆O	116.2		899.3	252.383		1.33783
	顺-2-戊烯醇（Z）-2-Penten1ol			1576-95-0		C₅H₁₀O	86.1		762.1	188.713		1.44506
	1-戊烯-3-醇Pent-1-en-3-ol			616-25-1		C₅H₁₀O	86.1		670.6	158.603		1.34867
	乙二醇二甲醚1，2-Dimethoxyethane			110-71-4		C₄H₁₀O₂	90.1		651.7	154.307		1.30380
	乙二醇丁醚2-Butoxyethanol			111-76-2		C₆H₁₄O₂	118.2		906.1	256.891		1.18231
	2-己醇2-Hexanol			626-93-7		C₆H₁₄O	102.2		816.3	210.419		1.26772
	4-己烯-1-醇4-Hexen-1-ol			6126-50-7		C₆H₁₂O	100.2		886.2	244.761		1.46307
	正己醇1-Hexanol			111-27-3		C₆H₁₄O	102.2		878.1	240.506		1.32130
	反式-2-己烯-1-醇（E）-2-Hexen-1-ol			928-95-0		C₆H₁₂O	100.2		873.4	238.081		1.18006
醛类Aldehydes	2-甲基丁醛2-Methylbutyraldehyde			96-17-3		C₅H₁₀O	86.1		661.5	156.524		1.16917
	2-己烯醛2-Hexenal			505-57-7		C₆H₁₀O	98.1		858.6	230.792		1.51165
	反式-2-庚醛Trans-2-Heptenal			18829-55-5		C₇H₁₂O	112.2		960.5	295.962		1.25501
	庚醛Heptanal			111-71-7		C₇H₁₄O	114.2		899.0	252.372		1.34091
	3-甲基-2-丁烯醛3-Methyl-2-butenal			107-86-8		C₅H₈O	84.1		775.5	193.022		1.11013
	正戊醛n-Pentanal			110-62-3		C₅H₁₀O	86.1		700.5	166.832		1.19381
	异戊醛3-Methyl butanal			590-86-3		C₅H₁₀O	86.1		656.4	155.592		1.18117
	（E,E）-2,4-己二烯醛（E,E）-2,4-Hexadienal			142-83-6		C₆H₈O	96.1		911.1	260.399		1.12014
	反式-2-己烯醛（E）-2-Hexenal			6728-26-3		C₆H₁₀O	98.1		832.5	217.925		1.18148
	反式-2-戊烯醛Trans-2-Pentenal			1576-87-0		C₅H₈O	84.1		749.9	183.655		1.10252
	正丁醛Butanal			123-72-8		C₄H₈O	72.1		592.0	141.750		1.28560
	2-甲基丙烯醛2-Methyl-2-propenal			78-85-3		C₄H₆O	70.1		579.6	139.235		1.05629
酸类Acids	2-甲基戊酸2-Methyl-pentanoic acid			97-61-0		C₆H₁₂O₂	116.2		956.9	293.057		1.25589
	丙酸Propanoic acid		79-09-4			C₃H₆O₂	74.1		735.9	179.018		1.10545
	异戊酸3-Methylbutanoic acid		503-74-2			C₅H₁₀O₂	102.1		850.2	226.431		1.51331
	丁酸Butanoic acid		107-92-6			C₄H₈O₂	88.1		790.4	198.949		1.40465
酮类Ketones	2-己酮2-Hexanone		591-78-6			C₆H₁₂O	100.2		775.3	193.758		1.18844
	3-辛酮3-Octanone		106-68-3			C₈H₁₆O	128.2		992.9	321.872		1.30203
	1-辛烯-3-酮1-octen-3-one		4312-99-6			C₈H₁₄O	126.2		981.1	312.219		1.27109
	环己酮Cyclohexanone		108-94-1			C₆H₁₀O	98.1		889.8	246.682		1.14241
	2-戊酮2-Pentanone		107-87-9			C₅H₁₀O	86.1		674.0	159.624		1.11070
	3-戊酮3-Pentanone		96-22-0			C₅H₁₀O	86.1		690.9	163.766		1.34928
	1-戊烯-3-酮1-Penten-3-one		1629-58-9			C₅H₈O	84.1		682.0	161.480		1.08078
	过氧化乙酰丙酮Acetoxyacetone		592-20-1			C₅H₈O₃	116.1		486.7	121.695		1.17657
烯烃类Alkenes	β-蒎烯（-）-β-Pinene		18172-67-3			C₁₀H₁₆	136.2		962.5	297.486		1.21913
酯类Esters	甲酸异戊酯Isopentyl formate		110-45-2			C₆H₁₂O₂	116.2		782.8	196.710		1.26577
	异丁酸乙酯Ethyl 2-methylpropanoate		97-62-1			C₆H₁₂O₂	116.2		755.3	186.152		1.19126
	丙烯酸乙酯Ethyl acrylate		140-88-5			C₅H₈O₂	100.1		698.1	165.948		1.42123
	甲酸丁酯Butyl formate		592-84-7			C₅H₁₀O₂	102.1		710.5	170.106		1.19209
	乙酸叶醇酯（Z）-3-hexenyl acetate		3681-71-8			C₈H₁₄O₂	142.2		1 013.1	342.702		1.32678
	巴豆酸乙酯Ethyl trans-2-butenoate		623-70-1			C₆H₁₀O₂	114.1		865.7	234.156		1.57582
	乙酸丁酯1-Butyl acetate		123-86-4			C₆H₁₂O₂	116.2		806.6	206.068		1.23544
	丁酸乙酯Ethyl butanoate		105-54-4			C₆H₁₂O₂	116.2		794.3	200.669		1.55681
	乙酸乙酯Acetic acid ethyl ester		141-78-6			C₄H₈O₂	88.1		602.6	143.930		1.09457
	乙酸甲酯Methyl acetate		79-20-9			C₃H₆O₂	74.1		555.5	134.447		1.19033
	乙酸己酯Hexyl acetate		142-92-7			C₈H₁₆O₂	144.2		1 008.4	337.531		1.40827
其他类Others	3-乙基-2-甲基吡嗪 2-Ethyl-3-methylpyrazine		15707-23-0			C₇H₁₀N₂	122.2		992.1	321.076		1.17599
	2,6-二甲基吡啶 2,6-Dimethylpyridine		108-48-5			C₇H₉N	107.2		887.2	245.193		1.46106
	2,5-二甲基呋喃2,5-Dimethylfuran		625-86-5			C₆H₈O	96.1		696.5	165.394		1.36108
	2-乙基呋喃2-Ethylfuran		3208-16-0			C₆H₈O	96.1		719.5	173.128		1.04219
	二丙基二硫Dipropyl disulfide		629-19-6			C₆H₁₄S₂	150.3		1 109.3	466.665		1.47526
类别 Type		化合物 Volatile compound			不同采摘期果皮挥发性成分峰面积 The peak area of the peel in different picking stages
类别 Type		化合物 Volatile compound			140 DAF			145 DAF			150 DAF
醇类Alcohols		3-庚醇3-Heptanol			289.67 ± 16.87			276.67 ± 13.94			265.76 ± 28.20
		顺-2-戊烯醇（Z）-2-Penten1ol			363.47 ± 23.72			278.65 ± 61.72			210.19 ± 34.51
		1-戊烯-3-醇Pent-1-en-3-ol			156.45 ± 1.86			148.64 ± 10.27			152.94 ± 2.90
		乙二醇二甲醚1，2-Dimethoxyethane			164.57 ± 21.30			183.53 ± 14.50			126.94 ± 17.74
		乙二醇丁醚2-Butoxyethanol			355.27 ± 10.17			368.37 ± 8.61			380.42 ± 21.07
		2-己醇2-Hexanol			ND			ND			ND
		4-己烯-1-醇4-Hexen-1-ol			131.04 ± 2.95			140.04 ± 17.23			129.54 ± 12.42
		正己醇1-Hexanol			46.05 ± 7.29			16.59 ± 1.85			14.24 ± 0.52
		反式-2-己烯-1-醇（E）-2-Hexen-1-ol			3 134.4 ± 10.62			3 111.35 ± 62.76			3 139.13 ± 49.57
醛类Aldehydes		2-甲基丁醛2-Methylbutyraldehyde			655.86 ± 33.58			552.26 ± 49.44			707.19 ± 13.05
		2-己烯醛2-Hexenal			18 125.60 ± 261.32			18 023.16 ± 333.01			17 921.4 ± 291.69
		反式-2-庚醛Trans-2-Heptenal			ND			ND			ND
		庚醛Heptanal			ND			ND			ND
		3-甲基-2-丁烯醛3-Methyl-2-butenal			ND			ND			ND
		正戊醛n-Pentanal			ND			ND			ND
		异戊醛3-Methyl butanal			ND			ND			ND
		（E,E）-2,4-己二烯醛（E,E）-2, 4-Hexadienal			236.13 ± 27.84			294.79 ± 71.87			272.48 ± 62.90
		反式-2-己烯醛（E）-2-Hexenal			522.73 ± 8.00			528.63 ± 23.47			542.06 ± 8.89
		反式-2-戊烯醛Trans-2-Pentenal			652.00 ± 11.27			656.85 ± 26.46			664.45 ± 13.58
		正丁醛Butanal			216.46 ± 4.02			163.57 ± 77.47			123.34 ± 21.30
		2-甲基丙烯醛2-Methyl-2-propenal			769.30 ± 66.34			700.40 ± 114.92			665.76 ± 30.30
酸类Acids		2-甲基戊酸2-Methyl-pentanoic acid			299.23 ± 8.83			288.85 ± 17.75			308.37 ± 30.19
		丙酸Propanoic acid			591.25 ± 13.66			603.87 ± 31.17			654.38 ± 3.58
		异戊酸3-Methylbutanoic acid			ND			ND			ND
		丁酸Butanoic acid			180.48 ± 4.54			165.61 ± 20.13			178.02 ± 5.67
酮类Ketones		2-己酮2-Hexanone			114.54 ± 4.74			113.60 ± 5.14			115.49 ± 2.27
		3-辛酮3-Octanone			ND			ND			ND
		1-辛烯-3-酮1-octen-3-one			ND			ND			ND
		环己酮Cyclohexanone			ND			ND			ND
		2-戊酮2-Pentanone			ND			ND			ND
		3-戊酮3-Pentanone			ND			ND			ND
		1-戊烯-3-酮1-Penten-3-one			188.86 ± 9.75			217.16 ± 2.15			301.87 ± 40.18
		过氧化乙酰丙酮Acetoxyacetone			691.52 ± 183.40			621.57 ± 54.21			549.11 ± 58.27
烯烃类Alkenes		β-蒎烯（-）-β-Pinene			94.88 ± 11.33			95.42 ± 18.69			91.44 ± 18.73
酯类Esters		甲酸异戊酯Isopentyl formate			146.47 ± 11.50			141.61 ± 9.70			148.83 ± 13.88
		异丁酸乙酯Ethyl 2-methylpropanoate			57.30 ± 2.81			58.42 ± 4.78			75.17 ± 5.33
		丙烯酸乙酯Ethyl acrylate			169.31 ± 9.19			195.61 ± 60.58			147.39 ± 9.43
		甲酸丁酯Butyl formate			1 545.28 ± 28.38			1 488.52 ± 191.94			1 786.14 ± 27.41
		乙酸叶醇酯（Z）-3-hexenyl acetate			ND			ND			ND
		巴豆酸乙酯Ethyl trans-2-butenoate			ND			ND			ND
		乙酸丁酯1-Butyl acetate			101.25 ± 4.74			63.72 ± 15.09			48.33 ± 3.58
		丁酸乙酯Ethyl butanoate			11 136.61 ± 349.64			11 024.93 ± 7.27			11 559.72 ± 231.53
		乙酸乙酯Acetic acid ethyl ester			1 279.46 ± 77.85			1 183.75 ± 379.92			1 107.19 ± 121.36
		乙酸甲酯Methyl acetate			248.17 ± 45.90			334.15 ± 65.70			176.14 ± 31.28
		乙酸己酯Hexyl acetate			180.77 ± 2.37			167.34 ± 18.10			174.45 ± 26.67
其他类Others		3-乙基-2-甲基吡嗪 2-Ethyl-3-methylpyrazine			291.71 ± 18.91			338.83 ± 17.25			292.43 ± 13.36
		2,6-二甲基吡啶2,6-Dimethylpyridine			104.68 ± 4.39			104.53 ± 10.99			106.77 ± 4.88
		2,5-二甲基呋喃2,5-Dimethylfuran			245.24 ± 2.51			230.30 ± 5.57			212.60 ± 10.63
		2-乙基呋喃2-Ethylfuran			ND			ND			ND
		二丙基二硫Dipropyl disulfide			777.05 ± 24.31			701.73 ± 25.55			394.89 ± 30.94
醇类Alcohols		3-庚醇3-Heptanol			ND			ND			ND
		顺-2-戊烯醇（Z）-2-Penten1ol			ND			ND			ND
		1-戊烯-3-醇Pent-1-en-3-ol			ND			ND			ND
		乙二醇二甲醚1，2-Dimethoxyethane			ND			ND			ND
		乙二醇丁醚2-Butoxyethanol			ND			ND			ND
		2-己醇2-Hexanol			2 511.61 ± 35.35			2 473.53 ± 67.51			2 306.54 ± 20.15
		4-己烯-1-醇4-Hexen-1-ol			83.37 ± 7.10			73.30 ± 5.49			80.03 ± 9.70
		正己醇1-Hexanol			214.77 ± 26.19			137.30 ±4 0.40			289.48 ± 92.09
		反式-2-己烯-1-醇（E）-2-Hexen-1-ol			2 691.55±128.98			2 582.66 ± 164.21			2 287.91 ± 226.15
醛类Aldehydes		2-甲基丁醛2-Methylbutyraldehyde			ND			ND			ND
		2-己烯醛2-Hexenal			ND			ND			ND
		反式-2-庚醛Trans-2-Heptenal			567.49 ± 36.42			535.37 ± 62.35			427.71 ± 67.28
		庚醛Heptanal			443.87 ± 36.92			382.24 ± 39.11			326.16 ± 40.41
		3-甲基-2-丁烯醛3-Methyl-2-butenal			119.27 ± 8.58			106.04 ± 3.00			114.69 ± 3.21
		正戊醛n-Pentanal			4 069.83 ± 81.83			4 009.21 ± 97.32			4 024.03 ± 70.64
		异戊醛3-Methyl butanal			289.50 ± 9.99			305.75 ± 19.82			277.66 ± 16.75
		（E,E）-2,4-己二烯醛（E,E）-2, 4-Hexadienal			41.38 ± 9.21			29.37 ± 6.95			29.34 ± 6.25
		反式-2-己烯醛（E）-2-Hexenal			861.86 ± 41.22			915.02 ± 27.66			974.39 ± 35.27
		反式-2-戊烯醛Trans-2-Pentenal			84.87 ± 8.51			72.72 ± 5.85			61.41 ± 6.13
		正丁醛Butanal			216.97 ± 22.39			222.41 ± 24.33			91.44 ± 23.56
		2-甲基丙烯醛2-Methyl-2-propenal			644.94 ± 18.75			541.88 ± 19.31			582.53 ± 16.63
酸类Acids		2-甲基戊酸2-Methyl-pentanoic acid			ND			ND			ND
		丙酸Propanoic acid			ND			ND			ND
		异戊酸3-Methylbutanoic acid			10 121.16 ± 86.88			8 822.95 ± 494.39			8 410.2 2± 392.84
		丁酸Butanoic acid			281.51 ± 8.79			269.43 ± 4.79			293.55 ± 2.41
酮类Ketones		2-己酮2-Hexanone			ND			ND			ND
		3-辛酮3-Octanone			71.55 ± 13.08			88.70 ± 16.07			102.35 ± 26.66
		1-辛烯-3-酮1-octen-3-one			234.81 ± 19.37			204.79 ± 30.31			129.73 ± 15.66
		环己酮Cyclohexanone			196.55 ± 13.13			175.53 ± 11.06			187.70 ± 6.14
		2-戊酮2-Pentanone			26.06 ± 3.14			26.98 ± 0.41			29.75 ± 1.38
		3-戊酮3-Pentanone			1 145.40 ± 59.47			1 058.28 ± 37.08			1 006.45 ± 51.49
		1-戊烯-3-酮1-Penten-3-one			261.60 ± 24.70			218.43 ± 14.40			193.89 ± 18.55
		过氧化乙酰丙酮Acetoxyacetone			570.85 ± 56.99			776.44 ± 70.76			458.48 ± 69.04
烯烃类Alkenes		β-蒎烯（-）-β-Pinene			74.42 ± 11.89			59.63 ± 11.52			58.90 ± 15.99
酯类Esters		甲酸异戊酯Isopentyl formate			ND			ND			ND
		异丁酸乙酯Ethyl 2-methylpropanoate			ND			ND			ND
		丙烯酸乙酯Ethyl acrylate			ND			ND			ND
		甲酸丁酯Butyl formate			ND			ND			ND
		乙酸叶醇酯（Z）-3-hexenyl acetate			62.65 ± 11.19			40.13 ± 7.46			26.89 ± 4.30
		巴豆酸乙酯Ethyl trans-2-butenoate			266.37 ± 70.37			336.66 ± 76.75			512.39 ± 51.63
		乙酸丁酯1-Butyl acetate			138.45 ± 9.40			121.19 ± 45.07			89.45 ± 13.99
		丁酸乙酯Ethyl butanoate			10 002.77 ± 84.56			9 549.11 ± 213.41			8 787.71 ± 251.88
		乙酸乙酯Acetic acid ethyl ester			1 240.37 ± 100.59			1 312.19 ± 137.25			845.61 ± 132.94
		乙酸甲酯Methyl acetate			349.65±149.14			456.5 ± 110.82			233.5 ± 52.94
		乙酸己酯Hexyl acetate			473.21 ± 80.62			326.13 ± 45.95			251.76 ± 37.56
其他类Others		3-乙基-2-甲基吡嗪 2-Ethyl-3-methylpyrazine			ND			ND			ND
		2,6-二甲基吡啶2,6-Dimethylpyridine			ND			ND			ND
		2,5-二甲基呋喃2,5-Dimethylfuran			ND			ND			ND
		2-乙基呋喃2-Ethylfuran			473.55 ± 22.12			403.84 ± 2.40			451.73 ± 39.80
		二丙基二硫Dipropyl disulfide			555.57 ± 75.44			330.14 ± 19.94			265.53 ± 7.71

类别 Type	化合物 Volatile compound	CAS号 Chemical Abstract Service			保留时间 RT		保留指数 RI
醇类Alcohols	正己醇1-Hexanol	111-27-3			14.7576		869
	1-壬醇1-Nonanol	143-08-8			27.0086		1 170
	2-甲基环戊醇Cyclopentanol,2-methyl-	24070-77-7			12.0792		798
	反-2-甲基环戊醇Cyclopentanol,2-methyl-,trans-	25144-04-1			12.0624		798
	环丁基甲醇Cyclobutanemethanol	4415-82-1			10.8612		767
	3-壬醇3-Nonanol	624-51-1			24.1480		1 095
	苏合香醇Benzenemethanol,alpha-methyl-	98-85-1			24.9862		1 118
醛类Aldehydes	十五醛Pentadecanal-	2765-11-9			35.3881		1614
	（E,E）-2,4-庚二烯醛（E,E）-2,4-Heptadienal	4313-03-5			20.7817		1 012
	苯甲醛Benzaldehyde	100-52-7			18.8081		964
	癸醛Decanal	112-31-2			28.3624		1 206
	苯乙醛Benzeneacetaldehyde	122-78-1			22.2278		1 048
	正辛醛Octanal	124-13-0			20.4453		1 003
	壬醛Nonanal	124-19-6			24.5123		1 105
	反式-2-壬烯醛（E）-2-Nonenal	18829-56-6			26.6686		1 161
	环己烷基甲醛Cyclohexanecarboxaldehyde	2043-61-0			18.5070		958
	反-2-辛烯醛（E）-2-Octenal	2548-87-0			22.7015		1 059
	3-乙基苯甲醛Benzaldehyde,3-ethyl-	34246-54-3			26.978		1 170
	反式-2-癸烯醛（E）-2-Decenal	3913-81-3			30.4131		1 264
	β-环柠檬醛β-Cyclocitral	432-25-7			29.1906		1 230
	4-乙基苯甲醛Benzaldehyde,4-ethyl-	4748-78-1			27.5739		1 185
	2-己烯醛2-Hexenal	505-57-7			14.1715		853
	（E,E）-2,4-壬二烯醛（E,E）-2,4-Nonadienal	5910-87-2			28.7231		1 216
	间苯二甲醛Isophthalaldehyde	626-19-7			29.6339		1 242
	2-甲基丁醛Butanal,2-methyl-	96-17-3			7.4433		668
酮类Ketones	甲基庚烯酮5-Hepten-2-one,6-methyl-	110-93-0			19.7912		988
	仲辛酮2-Octanone	111-13-7			19.9427		991
	甲基壬基甲酮2-Undecanone	112-12-9			31.4933		1 294
	4-甲基苯戊酮1-Pentanone，1-（4-methylphenyl）-	1671-77-8			27.3378		1 160
	橙化基丙酮Nerylacetone	3879-26-3			36.8451		1 456
	2-壬酮2-Nonanone	821-55-6			24.0160		1 092
	对乙基苯乙酮Ethanone,1-（4-ethylphenyl）-	937-30-4			31.3514		1 270
	苯乙酮Acetophenone	98-86-2			23.1772		1 071
烯烃类Alkenes	8-十七烷烯8-Heptadecene	16369-12-3			43.4658		1 678
	苯乙烯Styrene	100-42-5			15.8533		893
	花侧柏烯（+）-Cuparene	16982-00-6			38.0307		1 492
	α-法呢烯α-Farnesene	502-61-4			38.5762		1 511
酯类Esters	乙酸苯乙酯Acetic acid,2-phenylethyl ester	103-45-7			30.3184		1 261
	水杨酸甲酯Methyl salicylate	119-36-8			28.1945		1 202
	乙酸丁酯Acetic acid,butyl ester	123-86-4			12.4971		812
	乙酸己酯Acetic acid,hexyl ester	142-92-7			20.8096		1 013
	苯甲酸丙酯n-Propyl benzoate	2315-68-6			34.3940		1 380
	邻苯二甲酸二异丁酯Diisobutyl phthalate	84-69-5			48.7466		1 873
	邻苯二甲酸二丁酯Dibutyl phthalate	84-74-2			51.2549		1 966
	苯甲酸乙酯Benzoic acid,ethyl ester	93-89-0			27.1974		1 175
呋喃类Furans	2-乙基呋喃Furan,2-ethyl-	3208-16-0			8.7041		705
	2-正戊基呋喃Furan,2-pentyl-	3777-69-3			19.9995		993
	2-正丙基呋喃Furan2-propyl-	4229-91-8			20.1763		997
	2-甲基苯并呋喃Benzofuran，2-methyl-	4265-25-2			24.8807		1 114
	2-正丁基呋喃2-n-Butyl furan	4466-24-4			15.7786		893
其他类Others	左旋樟脑（-）-Camphor	464-48-2			26.4195		1 155
	醋酸Acetic acid	64-19-7			7.5842		674
	丁香酚Eugenol	97-53-0			33.8680		1 364
类别 Type	化合物 Volatile compound		不同采摘期果皮挥发性成分含量/（ng · g^-1） Volatile compounds content of peel at different picking stages
类别 Type	化合物 Volatile compound		140 DAF	145 DAF		150 DAF
醇类Alcohols	正己醇1-Hexanol		ND	ND		15.01 ± 4.88
	1-壬醇1-Nonanol		9.10 ± 2.24	11.67 ± 1.28		ND
	2-甲基环戊醇Cyclopentanol，2-methyl-		1323.05 ± 1037.26	ND		ND
	反-2-甲基环戊醇Cyclopentanol，2-methyl-,trans-		ND	ND		ND
	环丁基甲醇Cyclobutanemethanol		85.46 ± 84.95	ND		ND
	3-壬醇3-Nonanol		ND	ND		ND
	苏合香醇Benzenemethanol,.alpha.-methyl-		ND	2.04 ± 1.08		ND
醛类Aldehydes	十五醛Pentadecanal-		ND	4.16 ± 0.39		ND
	（E,E）-2,4-庚二烯醛（E,E）-2,4-Heptadienal		21.24 ± 2.61	29.02 ± 5.11		ND
	苯甲醛Benzaldehyde		411.77 ± 232.49	33.43 ± 4.91		ND
	癸醛Decanal		18.93 ± 9.87	18.81 ± 2.36		43.05 ± 21.31
	苯乙醛Benzeneacetaldehyde		37.38 ± 24.16	59.85 ± 6.38		45.06 ± 33.83
	正辛醛Octanal		24.42 ± 18.87	34.01 ± 8.33		38.69 ± 11.47
	壬醛Nonanal		219.35 ± 118.50	198.21 ± 34.61		138.33 ± 45.58
	反式-2-壬烯醛（E）-2-Nonenal		ND	ND		ND
	环己烷基甲醛Cyclohexanecarboxaldehyde		ND	ND		ND
	反-2-辛烯醛（E）-2-Octenal		ND	ND		ND
	3-乙基苯甲醛Benzaldehyde，3-ethyl-		ND	ND		40.11 ± 17.63
	反式-2-癸烯醛（E）-2-Decenal		41.22 ± 42.55	10.22 ± 0.47		24.54 ± 12.51
	β-环柠檬醛β-Cyclocitral		6.63 ± 2.60	5.59 ± 0.47		ND
	4-乙基苯甲醛Benzaldehyde，4-ethyl-		26.64 ± 14.63	15.76 ± 3.71		11.93 ± 3.54
	2-己烯醛2-Hexenal		4 474.10 ± 3388.29	6 185.75 ± 811.34		7 586.04 ± 2245.64
	（E,E）-2,4-壬二烯醛（E,E）-2,4-Nonadienal		ND	ND		ND
	间苯二甲醛Isophthalaldehyde		16.67 ± 4.39	19.74 ± 6.27		18.75 ± 12.17
	2-甲基丁醛Butanal，2-methyl-		ND	3.39 ± 0.41		ND
酮类Ketones	甲基庚烯酮5-Hepten-2-one，6-methyl-		23.12 ± 10.76	39.02 ± 5.44		29.10 ± 7.49
	仲辛酮2-Octanone		ND	5.01 ± 1.28		ND
	甲基壬基甲酮2-Undecanone		ND	3.05 ± 0.52		ND
	4-甲基苯戊酮1-Pentanone，1-（4-methylphenyl）-		3.84 ± 2.30	ND		8.02 ± 7.26
	橙化基丙酮Nerylacetone		ND	ND		ND
	2-壬酮2-Nonanone		ND	5.28 ± 0.98		ND
	对乙基苯乙酮Ethanone，1-（4-ethylphenyl）-		2 445.17 ± 1447.51	5.84 ± 1.74		ND
	苯乙酮Acetophenone		ND	7.91±0.78		ND
烯烃类Alkenes	8-十七烷烯8-Heptadecene		20.48 ± 13.65	52.04 ± 19.58		102.28 ± 12.11
	苯乙烯Styrene		ND	ND		19.61 ± 11.94
	花侧柏烯（+）-Cuparene		ND	3.48 ± 0.97		ND
	α-法呢烯α-Farnesene		354.57 ± 205.87	735.66 ± 289.00		ND
酯类Esters	乙酸苯乙酯Acetic acid，2-phenylethyl ester		ND	ND		328.95 ± 207.02
	水杨酸甲酯Methyl salicylate		7.58 ± 3.10	40.09 ± 33.08		ND
	乙酸丁酯Acetic acid，butyl ester		ND	ND		ND
	乙酸己酯Acetic acid，hexyl ester		9.62 ± 5.55	9.68 ± 4.90		6.75 ± 3.04
	苯甲酸丙酯n-Propyl benzoate		4.4 ± 0.98	ND		ND
	邻苯二甲酸二异丁酯Diisobutyl phthalate		ND	ND		ND
	邻苯二甲酸二丁酯Dibutyl phthalate		7.69 ± 2.85	4.70 ± 1.54		13.88 ± 5.04
	苯甲酸乙酯Benzoic acid，ethyl ester		7.18 ± 6.55	8.61 ± 6.37		8.72 ± 7.50
呋喃类Furans	2-乙基呋喃Furan，2-ethyl-		67.36 ± 34.74	69.59 ± 26.78		38.18 ± 17.89
	2-正戊基呋喃Furan,2-pentyl-		ND	ND		ND
	2-正丙基呋喃Furan2-propyl-		ND	ND		ND
	2-甲基苯并呋喃Benzofuran，2-methyl-		ND	ND		ND
	2-正丁基呋喃2-n-Butyl furan		ND	ND		ND
其他类Others	左旋樟脑（-）-Camphor		ND	ND		ND
	醋酸Acetic acid		13.95 ± 5.65	ND		68.22 ± 60.39
	丁香酚Eugenol		23.67 ± 19.23	5.05 ± 0.85		25.39 ± 21.01
醇类Alcohols	正己醇1-Hexanol		ND	ND		ND
	1-壬醇1-Nonanol		ND	ND		ND
	2-甲基环戊醇Cyclopentanol，2-methyl-		ND	ND		ND
	反-2-甲基环戊醇Cyclopentanol,2-methyl-,trans-	525.66 ± 259.45		1330.66 ± 591.93		1293.5 ± 354.11
	环丁基甲醇Cyclobutanemethanol	ND		ND		ND
	3-壬醇3-Nonanol	ND		3.84 ± 1.04		3.49 ± 0.70
	苏合香醇Benzenemethanol,.alpha.-methyl-	ND		ND		ND
醛类Aldehydes	十五醛Pentadecanal-	ND		ND		ND
	（E,E）-2,4-庚二烯醛（E,E）-2,4-Heptadienal	ND		ND		ND
	苯甲醛Benzaldehyde	ND		23.34 ± 8.64		21.37 ± 9.94
	癸醛Decanal	59.66 ± 7.88		42.53 ± 20.47		24.87 ± 4.44
	苯乙醛Benzeneacetaldehyde	ND		ND		22.08 ± 24.02
	正辛醛Octanal	64.38 ± 15.52		46.65 ± 14.14		29.63 ± 4.09
	壬醛Nonanal	224.50 ± 26.82		173.53 ± 36.35		124.93 ± 51.32
	反式-2-壬烯醛（E）-2-Nonenal	18.75 ± 2.60		ND		ND
	环己烷基甲醛Cyclohexanecarboxaldehyde	38.90 ± 10.35		ND		ND
	反-2-辛烯醛（E）-2-Octenal	34.42 ± 5.87		34.31 ± 21.16		19.37 ± 6.38
	3-乙基苯甲醛Benzaldehyde,3-ethyl-	11.58 ± 0.62		18.89 ± 11.03		16.88 ± 11.32
	反式-2-癸烯醛（E）-2-Decenal	19.14 ± 3.26		14.56 ± 5.74		10.17 ± 1.71
	β-环柠檬醛β-Cyclocitral	2.76 ± 0.37		3.11±1.66		ND
	4-乙基苯甲醛Benzaldehyde,4-ethyl-	3.87±0.10		6.68 ± 3.88		5.71 ± 4.18
	2-己烯醛2-Hexenal	704.82 ± 98.60		2 678.31 ± 2077.36		2 536.98 ± 1955.31
	（E,E）-2,4-壬二烯醛（E,E）-2,4-Nonadienal	7.86 ± 0.70		ND		ND
	间苯二甲醛Isophthalaldehyde	7.11 ± 0.68		12.75 ± 8.99		10.94 ± 9.45
	2-甲基丁醛Butanal,2-methyl-	ND		ND		ND
酮类Ketones	甲基庚烯酮5-Hepten-2-one,6-methyl-	ND		22.36 ± 13.68		ND
	仲辛酮2-Octanone	1.87 ± 0.21		3.24 ± 2.14		ND
	甲基壬基甲酮2-Undecanone	ND		ND		ND
	4-甲基苯戊酮1-Pentanone,1-（4-methylphenyl）-	ND		2.58 ± 1.39		ND
	橙化基丙酮Nerylacetone	12.65 ± 0.85		ND		ND
	2-壬酮2-Nonanone	ND		3.12 ± 1.94		ND
	对乙基苯乙酮Ethanone,1-（4-ethylphenyl）-	1.77 ± 0.72		3.5 ± 1.27		2.73 ± 1.68
	苯乙酮Acetophenone	ND		5.87 ± 1.07		ND
烯烃类Alkenes	8-十七烷烯8-Heptadecene	ND		ND		ND
	苯乙烯Styrene	5.85 ± 4.31		ND		ND
	花侧柏烯（+）-Cuparene	ND		ND		ND
	α-法呢烯α-Farnesene	ND		ND		362.63 ± 305.93
酯类Esters	乙酸苯乙酯Acetic acid,2-phenylethyl ester	58.16 ± 9.38		54.73 ± 48.26		370.43 ± 284.23
	水杨酸甲酯Methyl salicylate	ND		14.05 ± 9.77		ND
	乙酸丁酯Acetic acid,butyl ester	2.05 ± 0.11		ND		ND
	乙酸己酯Acetic acid,hexyl ester	15.42 ± 3.54		15.62 ± 1.19		9.66 ± 4.51
	苯甲酸丙酯n-Propyl benzoate	ND		ND		ND
	邻苯二甲酸二异丁酯Diisobutyl phthalate	9.33 ± 2.22		ND		ND
	邻苯二甲酸二丁酯Dibutyl phthalate	4.26 ± 0.91		7.01 ± 2.12		5.17 ± 1.39
	苯甲酸乙酯Benzoic acid，ethyl ester	0.80 ± 0.19		ND		5.99 ± 5.52
呋喃类Furans	2-乙基呋喃Furan,2-ethyl-	ND		33.77 ± 27.63		29.52 ± 27.90
	2-正戊基呋喃Furan,2-pentyl-	6.76 ± 2.76		ND		ND
	2-正丙基呋喃Furan2-propyl-	ND		4.06 ± 3.63		ND
	2-甲基苯并呋喃Benzofuran，2-methyl-	3.59 ± 0.65		ND		ND
	2-正丁基呋喃2-n-Butyl furan	1.79 ± 1.28		ND		ND
其他类Others	左旋樟脑（-）-Camphor	2.85 ± 0.37		ND		ND
	醋酸Acetic acid	ND		3.01 ± 0.77		7.05 ± 3.82
	丁香酚Eugenol	ND		ND		ND