腐植酸处理对樱桃番茄挥发性有机化合物成分和含量的影响

doi:10.16420/j.issn.0513-353x.2023-0811

摘要/Abstract

摘要：

以果实香气浓郁的樱桃番茄（Solanum lycopersicum var. cerasiforme）品种‘浙樱粉1号’为研究对象，采用顶空固相微萃取—气相色谱—质谱联用技术，对腐殖酸不同处理（对照：根部和叶面均施清水；根和叶施：根部和叶面均施腐植酸；根施：根部施腐植酸，叶面施清水；叶施：根部施清水，叶面施腐植酸）下果实挥发性有机化合物（volatile organic compounds，VOC）组成、含量及差异进行比较分析，共检测到15类340种VOC。与清水对照相比，根和叶施、根施、叶施腐殖酸处理后，果实中的VOC相对含量分别提升了49.3%、25.6%、14.4%，其中根和叶施、叶施处理显著提高了果实中醛类的相对含量，而根施处理显著提高了萜类的相对含量。差异VOC统计结果表明，与对照相比，根和叶施、根施、叶施腐植酸处理VOC积累上调数量分别为153、147和13个，占总差异积累VOC数量的97.5%、97.4%和81.3%，根和叶施、根施处理的差异VOC数量显著多于叶施处理。感官风味特征分析表明，根和叶施腐植酸能够增加番茄果实的甜香型香味特征，而单独根施和叶施处理则能够增加果香型香味特征。主成分分析结果表明：腐植酸处理后番茄果实香气特征不是被其中1或2种相对含量高或相对气味活度值较高的VOC主导，而是被多种VOC相互作用影响，使其呈现出不一样的香气类型。综上，腐殖酸处理，尤其是根和叶施处理，可显著影响番茄果实中VOC的组成和相对含量，提升风味品质。

关键词: 樱桃番茄, 腐植酸, 挥发性有机化合物, 相对含量, 风味特征

Abstract:

The cherry tomato cultivar‘Zheyingfen 1’，known for its abundant fruit flavor，was chosen as the experimental subject. The technique employed in this study involved the utilization of headspace solid phase microextraction coupled with gas chromatography-mass spectrometry. The present study aimed to compare and analyze the compositions，contents，and variations of volatile organic compounds（VOCs）in fruits subjected to humic acid treatment（control）apply water to the root and leaf surface；root and leaf application：humic acid is applied to both root and leaf surface；root application：humic acid on root and water on leaf surface；leaf application：root application of water，leaf surface application of humic acid. A comprehensive analysis revealed the detection of a total of 15 categories and 340 distinct types of VOCs. In comparison to water control，the contents of VOCs in fruits exhibited a relative increase of 49.3%，25.6%，and 14.4% when humic acid was applied to the leaves，roots，and leaves respectively. Moreover，the contents of aldehydes in fruits significantly increased with both root and leaf application of humic acid，whereas the contents of terpenes were significantly elevated solely with root application. The statistical analysis of differential VOCs revealed that，in comparison to the control group，the up-regulated VOCs resulting from the application of humic acid to both roots and leaves，solely to roots，and solely to leaves were 153，147，and 13，respectively. These values accounted for 97.5%，97.4% and 81.3% of the total differential VOCs. Notably，the differential VOCs observed in the combined root and leaf application and the sole root application were significantly greater than those observed in the sole leaf application. The examination of sensory flavor attributes revealed that the application of humic acid to both the root and leaf of tomato plants resulted in an augmentation of the sweet flavor characteristics in the fruits. Conversely，solely applying humic acid to either the root or leaf led to an enhancement of the fruity flavor characteristics. The findings from the principal component analysis indicate that the aroma attributes of tomato fruits following humic acid treatment are not primarily governed by a few VOCs with substantial relative content or high relative odor activity value. Instead，they are influenced by the interplay of multiple VOCs，resulting in distinct aroma profiles. Consequently，the application of humic acid treatment，particularly through root and leaf administration，exerts a significant impact on the composition and relative content of VOCs in tomato fruits，thereby enhancing their flavor quality.

Key words: Solanum lycopersicum var. cerasiforme, humic acid treatment, volatile organic compounds, relative content, sensory flavor characteristics

关思慧, 刘晨旭, 姚祝平, 万红建, 刁明, 程远. 腐植酸处理对樱桃番茄挥发性有机化合物成分和含量的影响[J]. 园艺学报, 2024, 51(2): 346-360.

GUAN Sihui, LIU Chenxu, YAO Zhuping, WAN Hongjian, DIAO Ming, CHENG Yuan. Effects of Humic Acid Treatment on the Composition and Content of Volatile Organic Compounds in Cherry Tomato[J]. Acta Horticulturae Sinica, 2024, 51(2): 346-360.

图/表 7

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处理 Treatment	化合物名称 Name	种类 Type	CAS	上调差异倍数 Fold change
根和叶施	丁酸环戊酯 Butanoic acid, cyclopentyl ester	酯类 Esters	6290-13-7	—
Root	顺-7-癸烯醛 cis-7-Decen-1-al	醛类 Aldehydes	21661-97-2	—
and	3-乙基-2,6-哌啶二酮 2,6-Piperidinedione, 3-ethyl-	杂环类 Heterocyclics	25115-69-9	—
leaf	6-硝基-2-吡啶啉 2-Picoline，6-nitro-	杂环类 Heterocyclics	18368-61-1	—
application	松油烯 1,3-Cyclohexadiene, 1-methyl-4-(1-methylethyl)-	萜类 Terpenoids	99-86-5	3.95
	己酸丙酯 Hexanoic acid，propyl ester	酯类 Esters	626-77-7	3.27
	2-壬醇 2-Nonanol	醇类 Alcohols	628-99-9	2.86
	4-异丙基甲苯 p-Cymene	芳烃 Aromatics	99-87-6	2.65
	异丁酸异丁酯 Propanoic acid, 2-methyl-, 2-methylpropyl ester	酯类 Esters	97-85-8	2.40
	2,4-己二醛 2,4-Hexadienal, (E, E)-	醛类 Aldehydes	142-83-6	2.34
	1,3,3-三甲基-二环[2.2.1]庚-2-酮 Fenchone	萜类 Terpenoids	1195-79-5	2.33
	2-甲基-壬烷 Nonane, 2-methyl-	烃类 Hydrocarbons	871-83-0	2.31
	（1-硝基丙基）-苯 Benzene, (1-nitropropyl)-	芳烃 Aromatics	5279-14-1	2.27
	2-甲基-十七烷 Heptadecane, 2-methyl-	烃类 Hydrocarbons	1560-89-0	2.10
	α-松油醇 L-α-Terpineol	萜类 Terpenoids	10482-56-1	2.08
根施	丁酸环戊酯 Butanoic acid, cyclopentyl ester	酯类 Esters	6290-13-7	—
Root	顺-7-癸烯醛 cis-7-Decen-1-al	醛类 Aldehydes	21661-97-2	—
application	3-乙基-2,6-哌啶二酮 2,6-Piperidinedione, 3-ethyl-	杂环类 Heterocyclics	25115-69-9	—
	6-硝基-2-吡啶啉 2-Picoline, 6-nitro-	杂环类 Heterocyclics	18368-61-1	—
	2-丁基四氢呋喃 Furan, 2-butyltetrahydro-	杂环类 Heterocyclics	1004-29-1	—
	2-甲基-戊酸 Pentanoic acid, 2-methyl-	酸类 Acids	97-61-0	—
	顺-3-己烯基丁酸酯Butanoic acid, 3-hexenyl ester, (Z)-	酯类 Esters	16491-36-4	—
	2-乙酰基吡咯烷 2-Acetylpyrrolidine	杂环类 Heterocyclics	60026-20-2	—
	松油烯 1,3-Cyclohexadiene, 1-methyl-4-(1-methylethyl)-	萜类 Terpenoids	99-86-5	3.54
	2-甲基-十七烷 Heptadecane, 2-methyl-	烃类 Hydrocarbons	1560-89-0	2.54
	1-十二碳烯 1-Dodecene	烃类 Hydrocarbons	112-41-4	2.40
	（1-硝基丙基）-苯 Benzene, (1-nitropropyl)-	芳烃 Aromatics	5279-14-1	2.25
	1-甲基-4-（1-甲基亚乙基）-环己醇 1-Cyclohexanol, 1-methyl-4-(1-methylethylidene)-	萜类 Terpenoids	586-81-2	2.17
	4-甲基-十五烷 Pentadecane, 4-methyl-	烃类 Hydrocarbons	2801-87-8	2.14
	2-呋喃丙酸乙酯 2-Furanpropanoic acid, ethyl ester	杂环类 Heterocyclics	10031-90-0	2.13
	顺式对甲酚 p-Menth-2-en-7-ol, cis-	酚类 Phenols	19898-86-3	2.08
	2-甲基-十五烷 Pentadecane, 2-methyl-	烃类 Hydrocarbons	1560-93-6	2.08
	（1S-顺式）-2,3,5,7a-四氢-1-羟基-1H-吡咯嗪7-甲醇 1H-Pyrrolizine-7-methanol, 2,3,5,7a-tetrahydro-1-hydroxy-, (1S-cis)-	杂环类 Heterocyclics	520-63-8	2.07
	4- （1-甲基乙烯基）-1-环己烯-1-羧酸 1-Cyclohexene-1-carboxylic acid, 4-(1-methylethenyl)-	萜类 Terpenoids	7694-45-3	2.04
	(Z)-3,3-二甲基环亚己基乙醇 Ethanol, 2-(3,3-dimethylcyclohexylidene)-，(Z)-	醇类 Alcohols	26532-23-0	2.01
	二甲基丁酸叶醇酯 cis-3-Hexenyl-α-methylbutyrate	酯类 Esters	53398-85-9	2.01
	7-羟基-6-甲基-呋喃[3,4-c]吡啶-1（3H）-酮 Furo[3,4-c]pyridin-1(3H)-one, 7-hydroxy-6-methyl-	杂环类 Heterocyclics	4753-19-9	2.00
叶施	丁酸环戊酯 Butanoic acid, cyclopentyl ester	酯类 Esters	6290-13-7	—
Leaf	顺-7-癸烯醛 cis-7-Decen-1-al	醛类 Aldehydes	21661-97-2	—
application	3-乙基-2,6-哌啶二酮 2,6-Piperidinedione, 3-ethyl-	杂环类 Heterocyclics	25115-69-9	—
	6-硝基-2-吡啶啉 2-Picoline, 6-nitro-	杂环类 Heterocyclics	18368-61-1	—
	2-丁基四氢呋喃 Furan, 2-butyltetrahydro-	杂环类 Heterocyclics	1004-29-1	—
	2-甲基-戊酸 Pentanoic acid, 2-methyl-	酸类 Acids	97-61-0	—
	顺-3-己烯基丁酸酯 Butanoic acid, 3-hexenyl ester, (Z)-	酯类 Esters	16491-36-4	—
	4-（1-甲基乙基）-1,5-环己二烯-1-甲醇 1,5-Cyclohexadiene-1-methanol, 4-(1-methylethyl)-	萜类 Terpenoids	19876-45-0	2.65
	四甲基十四烷 Tetradecane, 4-methyl-	烃类 Hydrocarbons	25117-24-2	2.09

处理 Treatment	化合物名称 Name	种类 Type	CAS	上调差异倍数 Fold change
根和叶施	丁酸环戊酯 Butanoic acid, cyclopentyl ester	酯类 Esters	6290-13-7	—
Root	顺-7-癸烯醛 cis-7-Decen-1-al	醛类 Aldehydes	21661-97-2	—
and	3-乙基-2,6-哌啶二酮 2,6-Piperidinedione, 3-ethyl-	杂环类 Heterocyclics	25115-69-9	—
leaf	6-硝基-2-吡啶啉 2-Picoline，6-nitro-	杂环类 Heterocyclics	18368-61-1	—
application	松油烯 1,3-Cyclohexadiene, 1-methyl-4-(1-methylethyl)-	萜类 Terpenoids	99-86-5	3.95
	己酸丙酯 Hexanoic acid，propyl ester	酯类 Esters	626-77-7	3.27
	2-壬醇 2-Nonanol	醇类 Alcohols	628-99-9	2.86
	4-异丙基甲苯 p-Cymene	芳烃 Aromatics	99-87-6	2.65
	异丁酸异丁酯 Propanoic acid, 2-methyl-, 2-methylpropyl ester	酯类 Esters	97-85-8	2.40
	2,4-己二醛 2,4-Hexadienal, (E, E)-	醛类 Aldehydes	142-83-6	2.34
	1,3,3-三甲基-二环[2.2.1]庚-2-酮 Fenchone	萜类 Terpenoids	1195-79-5	2.33
	2-甲基-壬烷 Nonane, 2-methyl-	烃类 Hydrocarbons	871-83-0	2.31
	（1-硝基丙基）-苯 Benzene, (1-nitropropyl)-	芳烃 Aromatics	5279-14-1	2.27
	2-甲基-十七烷 Heptadecane, 2-methyl-	烃类 Hydrocarbons	1560-89-0	2.10
	α-松油醇 L-α-Terpineol	萜类 Terpenoids	10482-56-1	2.08
根施	丁酸环戊酯 Butanoic acid, cyclopentyl ester	酯类 Esters	6290-13-7	—
Root	顺-7-癸烯醛 cis-7-Decen-1-al	醛类 Aldehydes	21661-97-2	—
application	3-乙基-2,6-哌啶二酮 2,6-Piperidinedione, 3-ethyl-	杂环类 Heterocyclics	25115-69-9	—
	6-硝基-2-吡啶啉 2-Picoline, 6-nitro-	杂环类 Heterocyclics	18368-61-1	—
	2-丁基四氢呋喃 Furan, 2-butyltetrahydro-	杂环类 Heterocyclics	1004-29-1	—
	2-甲基-戊酸 Pentanoic acid, 2-methyl-	酸类 Acids	97-61-0	—
	顺-3-己烯基丁酸酯Butanoic acid, 3-hexenyl ester, (Z)-	酯类 Esters	16491-36-4	—
	2-乙酰基吡咯烷 2-Acetylpyrrolidine	杂环类 Heterocyclics	60026-20-2	—
	松油烯 1,3-Cyclohexadiene, 1-methyl-4-(1-methylethyl)-	萜类 Terpenoids	99-86-5	3.54
	2-甲基-十七烷 Heptadecane, 2-methyl-	烃类 Hydrocarbons	1560-89-0	2.54
	1-十二碳烯 1-Dodecene	烃类 Hydrocarbons	112-41-4	2.40
	（1-硝基丙基）-苯 Benzene, (1-nitropropyl)-	芳烃 Aromatics	5279-14-1	2.25
	1-甲基-4-（1-甲基亚乙基）-环己醇 1-Cyclohexanol, 1-methyl-4-(1-methylethylidene)-	萜类 Terpenoids	586-81-2	2.17
	4-甲基-十五烷 Pentadecane, 4-methyl-	烃类 Hydrocarbons	2801-87-8	2.14
	2-呋喃丙酸乙酯 2-Furanpropanoic acid, ethyl ester	杂环类 Heterocyclics	10031-90-0	2.13
	顺式对甲酚 p-Menth-2-en-7-ol, cis-	酚类 Phenols	19898-86-3	2.08
	2-甲基-十五烷 Pentadecane, 2-methyl-	烃类 Hydrocarbons	1560-93-6	2.08
	（1S-顺式）-2,3,5,7a-四氢-1-羟基-1H-吡咯嗪7-甲醇 1H-Pyrrolizine-7-methanol, 2,3,5,7a-tetrahydro-1-hydroxy-, (1S-cis)-	杂环类 Heterocyclics	520-63-8	2.07
	4- （1-甲基乙烯基）-1-环己烯-1-羧酸 1-Cyclohexene-1-carboxylic acid, 4-(1-methylethenyl)-	萜类 Terpenoids	7694-45-3	2.04
	(Z)-3,3-二甲基环亚己基乙醇 Ethanol, 2-(3,3-dimethylcyclohexylidene)-，(Z)-	醇类 Alcohols	26532-23-0	2.01
	二甲基丁酸叶醇酯 cis-3-Hexenyl-α-methylbutyrate	酯类 Esters	53398-85-9	2.01
	7-羟基-6-甲基-呋喃[3,4-c]吡啶-1（3H）-酮 Furo[3,4-c]pyridin-1(3H)-one, 7-hydroxy-6-methyl-	杂环类 Heterocyclics	4753-19-9	2.00
叶施	丁酸环戊酯 Butanoic acid, cyclopentyl ester	酯类 Esters	6290-13-7	—
Leaf	顺-7-癸烯醛 cis-7-Decen-1-al	醛类 Aldehydes	21661-97-2	—
application	3-乙基-2,6-哌啶二酮 2,6-Piperidinedione, 3-ethyl-	杂环类 Heterocyclics	25115-69-9	—
	6-硝基-2-吡啶啉 2-Picoline, 6-nitro-	杂环类 Heterocyclics	18368-61-1	—
	2-丁基四氢呋喃 Furan, 2-butyltetrahydro-	杂环类 Heterocyclics	1004-29-1	—
	2-甲基-戊酸 Pentanoic acid, 2-methyl-	酸类 Acids	97-61-0	—
	顺-3-己烯基丁酸酯 Butanoic acid, 3-hexenyl ester, (Z)-	酯类 Esters	16491-36-4	—
	4-（1-甲基乙基）-1,5-环己二烯-1-甲醇 1,5-Cyclohexadiene-1-methanol, 4-(1-methylethyl)-	萜类 Terpenoids	19876-45-0	2.65
	四甲基十四烷 Tetradecane, 4-methyl-	烃类 Hydrocarbons	25117-24-2	2.09

化合物 Compound	PC1		PC2
化合物 Compound	载荷量 Load capacity	特征向量 Feature vector	载荷量 Load capacity	特征向量 Feature vector
顺-4-庚烯醛 4-Heptenal, (Z)-	0.878	0.033	-0.479	-0.031
5-甲基-2-呋喃甲硫醇 2-Furanmethanethiol, 5-methyl-	0.748	0.028	-0.664	-0.042
2-噻吩甲基硫醇 2-Thiophenemethanethiol	0.974	0.037	0.224	0.014
二甲基三硫 Dimethyl triSulfur compounds	0.998	0.038	0.058	0.004
苯甲硫醇 Benzenemethanethiol	0.344	0.013	-0.939	-0.060
5-乙基-3-羟基-4-甲基-2(5H)-呋喃酮 2(5H)-Furanone, 5-ethyl-3-hydroxy-4-methyl-	0.971	0.037	0.240	0.015
己醛 Hexanal	0.542	0.021	-0.841	-0.054
(E)-2-壬烯醛 2-Nonenal, (E)-	-1.000	-0.038	0.026	0.002
1-辛烯-3-酮 1-Octen-3-one	0.950	0.036	-0.313	-0.020
甲酸-3-巯基-3-甲基丁酯 3-Mercapto-3-methylbutyl formate (ester)	-0.307	-0.012	0.952	0.061
丁酸环戊酯 Butanoic acid，cyclopentyl ester	0.963	0.037	-0.269	-0.017
顺-7-癸烯醛 cis-7-Decen-1-al	0.639	0.024	0.770	0.049
3-乙基-2,6-哌啶二酮 2,6-Piperidinedione, 3-ethyl-	0.682	0.026	0.731	0.047
6-硝基-2-吡啶啉 2-Picoline，6-nitro-	-0.961	-0.036	0.278	0.018
异丁酸异丁酯 Propanoic acid, 2-methyl-, 2-methylpropyl ester	0.837	0.032	-0.548	-0.035
1,3,3-三甲基-二环[2.2.1]庚-2-酮 Fenchone	0.450	0.017	-0.893	-0.057
2,4-己二醛 2,4-Hexadienal, (E, E)-	0.738	0.028	-0.675	-0.043
2-甲基-十七烷 Heptadecane, 2-methyl-	0.509	0.019	0.861	0.055
2-壬醇 2-Nonanol	0.782	0.030	-0.623	-0.040
己酸丙酯 Hexanoic acid, propyl ester	0.912	0.035	-0.411	-0.026
2-甲基-壬烷 Nonane, 2-methyl-	0.987	0.037	-0.162	-0.010
4-异丙基甲苯 p-Cymene	0.809	0.031	0.587	0.037
α-松油醇 L-α-Terpineol	0.003	0.000	-1.000	-0.064
（1-硝基丙基）-苯 Benzene, (1-nitropropyl)-	0.974	0.037	0.227	0.014
松油烯 1，3-Cyclohexadiene, 1-methyl-4-(1-methylethyl)-	0.990	0.038	-0.141	-0.009
(Z)-3, 3-二甲基环亚己基乙醇 Ethanol, 2-(3,3-dimethylcyclohexylidene)-, (Z)-	0.773	0.029	0.635	0.041
1-十二碳烯 1-Dodecene	0.208	0.008	0.978	0.062
2-呋喃丙酸乙酯 2-Furanpropanoic acid，ethyl ester	-0.911	-0.035	-0.412	-0.026
1-甲基-4-（1-甲基亚乙基）-环己醇 Cyclohexanol, 1-methyl-4-(1-methylethylidene)-	-1.000	-0.038	0.000	0.000
顺式对甲酚 p-Menth-2-en-7-ol, cis-	-0.957	-0.036	-0.291	-0.019
4- （1-甲基乙烯基）-1-环己烯-1-羧酸 1-Cyclohexene-1-carboxylic acid, 4-(1-methylethenyl)-	0.661	0.025	0.751	0.048
（1S-顺式）-2,3,5,7a-四氢-1-羟基-1H-吡咯嗪7-甲醇 1H-Pyrrolizine-7-methanol, 2,3,5,7a-tetrahydro-1-hydroxy-，(1S-cis)-	0.685	0.026	0.728	0.046
2-甲基-十五烷 Pentadecane, 2-methyl-	0.899	0.034	0.438	0.028
4-甲基-十五烷 Pentadecane, 4-methyl-	0.741	0.028	0.671	0.043

化合物 Compound	PC1		PC2
化合物 Compound	载荷量 Load capacity	特征向量 Feature vector	载荷量 Load capacity	特征向量 Feature vector
顺-4-庚烯醛 4-Heptenal, (Z)-	0.878	0.033	-0.479	-0.031
5-甲基-2-呋喃甲硫醇 2-Furanmethanethiol, 5-methyl-	0.748	0.028	-0.664	-0.042
2-噻吩甲基硫醇 2-Thiophenemethanethiol	0.974	0.037	0.224	0.014
二甲基三硫 Dimethyl triSulfur compounds	0.998	0.038	0.058	0.004
苯甲硫醇 Benzenemethanethiol	0.344	0.013	-0.939	-0.060
5-乙基-3-羟基-4-甲基-2(5H)-呋喃酮 2(5H)-Furanone, 5-ethyl-3-hydroxy-4-methyl-	0.971	0.037	0.240	0.015
己醛 Hexanal	0.542	0.021	-0.841	-0.054
(E)-2-壬烯醛 2-Nonenal, (E)-	-1.000	-0.038	0.026	0.002
1-辛烯-3-酮 1-Octen-3-one	0.950	0.036	-0.313	-0.020
甲酸-3-巯基-3-甲基丁酯 3-Mercapto-3-methylbutyl formate (ester)	-0.307	-0.012	0.952	0.061
丁酸环戊酯 Butanoic acid，cyclopentyl ester	0.963	0.037	-0.269	-0.017
顺-7-癸烯醛 cis-7-Decen-1-al	0.639	0.024	0.770	0.049
3-乙基-2,6-哌啶二酮 2,6-Piperidinedione, 3-ethyl-	0.682	0.026	0.731	0.047
6-硝基-2-吡啶啉 2-Picoline，6-nitro-	-0.961	-0.036	0.278	0.018
异丁酸异丁酯 Propanoic acid, 2-methyl-, 2-methylpropyl ester	0.837	0.032	-0.548	-0.035
1,3,3-三甲基-二环[2.2.1]庚-2-酮 Fenchone	0.450	0.017	-0.893	-0.057
2,4-己二醛 2,4-Hexadienal, (E, E)-	0.738	0.028	-0.675	-0.043
2-甲基-十七烷 Heptadecane, 2-methyl-	0.509	0.019	0.861	0.055
2-壬醇 2-Nonanol	0.782	0.030	-0.623	-0.040
己酸丙酯 Hexanoic acid, propyl ester	0.912	0.035	-0.411	-0.026
2-甲基-壬烷 Nonane, 2-methyl-	0.987	0.037	-0.162	-0.010
4-异丙基甲苯 p-Cymene	0.809	0.031	0.587	0.037
α-松油醇 L-α-Terpineol	0.003	0.000	-1.000	-0.064
（1-硝基丙基）-苯 Benzene, (1-nitropropyl)-	0.974	0.037	0.227	0.014
松油烯 1，3-Cyclohexadiene, 1-methyl-4-(1-methylethyl)-	0.990	0.038	-0.141	-0.009
(Z)-3, 3-二甲基环亚己基乙醇 Ethanol, 2-(3,3-dimethylcyclohexylidene)-, (Z)-	0.773	0.029	0.635	0.041
1-十二碳烯 1-Dodecene	0.208	0.008	0.978	0.062
2-呋喃丙酸乙酯 2-Furanpropanoic acid，ethyl ester	-0.911	-0.035	-0.412	-0.026
1-甲基-4-（1-甲基亚乙基）-环己醇 Cyclohexanol, 1-methyl-4-(1-methylethylidene)-	-1.000	-0.038	0.000	0.000
顺式对甲酚 p-Menth-2-en-7-ol, cis-	-0.957	-0.036	-0.291	-0.019
4- （1-甲基乙烯基）-1-环己烯-1-羧酸 1-Cyclohexene-1-carboxylic acid, 4-(1-methylethenyl)-	0.661	0.025	0.751	0.048
（1S-顺式）-2,3,5,7a-四氢-1-羟基-1H-吡咯嗪7-甲醇 1H-Pyrrolizine-7-methanol, 2,3,5,7a-tetrahydro-1-hydroxy-，(1S-cis)-	0.685	0.026	0.728	0.046
2-甲基-十五烷 Pentadecane, 2-methyl-	0.899	0.034	0.438	0.028
4-甲基-十五烷 Pentadecane, 4-methyl-	0.741	0.028	0.671	0.043